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emmasim [6.3K]
2 years ago
6

Why doesn’t the KHP concentration have to be exactly 0.100M? Explain using complete sentences.

Chemistry
1 answer:
ollegr [7]2 years ago
8 0

Answer:

The answer is in the explanation.

Explanation:

The KHP is an acid used as standard in titrations to find concentration of bases as NaOH.

The reaction that explain this use is:

KHP + NaOH → KNaP + H2O

<em>where 1 mole of KHP reacts per mole of NaOH</em>

That means, at equivalence point of a titration in which titrant is NaOH, the moles of KHP = Moles of NaOH added

With the moles of KHP = Moles of NaOH and the volume used by titrant we can find the molar concentration of NaOH.

The moles of KHP are obtained from the volume and the concentration as follows:

Volume(L)*Concentration (Molarity,M) = moles of KHP

If the concentration is more or less than 0.100M, the moles will be higher or lower. For that reason, we need to know the concentration of KHP but is not necessary to be 0.100M.

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Be sure to answer all parts. for each reaction, find the value of δso. report the value with the appropriate sign. (a) 3 no2(g)
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Answer:

Change in entropy for the reaction is

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Explanation:

To calculate the change in entropy for the balanced reaction, we require the natural entropy of all the reactants and products in the reaction.

3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)

From Literature.

S°(NO₂) = 240.06 J/K.mol

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These are the entropies of the reactants and products under standard conditions of 298.15 K and 1 atm.

Note that

ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)

Σ nᵢS°(for products) = [2 × S°(HNO₃)] + [1 × S°(NO)]

= (2 × 155.60) + (1 × 210.76) = 521.96 J/K.mol

Σ nᵢS°(for reactants) = [3 × S°(NO₂)] + [1 × S°(H₂O)]

= (3 × 240.06) + (1 × 69.91) =790.09 J/K.mol

ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)

ΔS° = 521.96 - 790.09 = -268.13 J/K.mol

Hope this Helps!!

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