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Ahat [919]
2 years ago
10

Under what conditions is the change in internal energy, δe rxn , equal to the heat evolved in a chemical reaction?

Chemistry
1 answer:
Stells [14]2 years ago
4 0
 the first law says that  the change in internal energy of a system is given by: 

δ<span>E = δq + δw</span>

where δ<span>E is the i change in internal energy, </span>

<span>δq is the amount of thermal energy added to the system from the surroundings </span>

<span>δw is the l work done *on* the system *by* the surroundings. </span>

<span>For a system only undergoing expansion work,
δw = -p</span>δ<span>V, so: </span>

δE = δq - p δ<span>V </span>
when δV = 0, then δe=δq
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