Boiling-point elevation is a colligative property.
That means, the the boiling-point elevation depends on the molar content (fraction) of solute.
The dependency is ΔTb = Kb*m
Where ΔTb is the elevation in the boiling point, kb is the boiling constant, and m is the molality.
A solution of 6.00 g of Ca(NO3) in 30.0 g of water has 4 times the molal concentration of a solution of 3.00 g of Ca(NO3)2 in 60.0 g of water.:
(6.00g/molar mass) / 0.030kg = 200 /molar mass (3.00g/molar mass) / 0.060kg = 50/molar mass
=> 200 / 50 = 4.
Then, given the direct proportion of the elevation of the boiling point with the molal concentration, the solution of 6.00 g of CaNO3 in 30 g of water will exhibit a greater boiling point elevation.
Or, what is the same, the solution with higher molality will have the higher boiling point.
In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases of that substance coexist in thermodynamic equilibrium. It is that temperatureand pressure at which the sublimation curve, fusion curve and vaporisation curve meet.
