Answer:
2.4 moles of oxygen are needed to react with 87 g of aluminium.
Explanation:
Chemical equation:
4Al(s) + 3O₂(l) → 2AlO₃(s)
Given data:
Mass of aluminium = 87 g
Moles of oxygen needed = ?
Solution:
Moles of aluminium:
Number of moles of aluminium= Mass/ molar mass
Number of moles of aluminium= 87 g/ 27 g/mol
Number of moles of aluminium= 3.2 mol
Now we will compare the moles of aluminium with oxygen.
Al : O₂
4 : 3
3.2 : 3/4×3.2 = 2.4 mol
2.4 moles of oxygen are needed to react with 87 g of aluminium.
Answer : The entropy change for the surroundings of the reaction is, -198.3 J/K
Explanation :
We have to calculate the entropy change of reaction 
.
![\Delta S^o=[n_{NH_3}\times \Delta S^0_{(NH_3)}]-[n_{N_2}\times \Delta S^0_{(N_2)}+n_{H_2}\times \Delta S^0_{(H_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BNH_3%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28NH_3%29%7D%5D-%5Bn_%7BN_2%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28N_2%29%7D%2Bn_%7BH_2%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28H_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of 
= standard entropy of 
= standard entropy of 
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (192.5J/K.mole)]-[1mole\times (191.5J/K.mole)+3mole\times (130.6J/K.mole)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28192.5J%2FK.mole%29%5D-%5B1mole%5Ctimes%20%28191.5J%2FK.mole%29%2B3mole%5Ctimes%20%28130.6J%2FK.mole%29%5D)
Therefore, the entropy change for the surroundings of the reaction is, -198.3 J/K
We need (i) the stoichiometric equation, and (ii) the equivalent mass of dihydrogen.
Explanation:
1
2
N
2
(
g
)
+
3
2
H
2
(
g
)
→
N
H
3
(
g
)
11.27
g
of ammonia represents
11.27
⋅
g
17.03
⋅
g
⋅
m
o
l
−
1
=
?
?
m
o
l
.
Whatever this molar quantity is, it is clear from the stoichiometry of the reaction that 3/2 equiv of dihydrogen gas were required. How much dinitrogen gas was required?
