I can't see the picture, but in general, I believe it is in dropping from the first energy level above the ground state, to the ground state.
The answer is to increase the surface area of the solute.
You see it dissolves faster because there is a lot more water touching it when it is has a higher surface area.This can be achieved by crushing
1 is element 2 is element 3 is compound 4 is element 5 is nothing in and water is a compound