It depends on the process.
Like for example if the process is isothermal(temperature is constant), you can use,
PV = constant or P1V1 = P2V2 where P1V1 are initial conditions and P2V2 are final.
For adiabatic process,
PV^gamma = constant or P1V1 ^gamma = P2V2 ^gamma.
where gamma = Cp
------
Cv
Cp = specific heat at constant pressure and Cv = specific at constant volume.
Value of Gamma will be given in question.
Hope this helps!
Chlorine. Electronegativity generally increases up and across the periodic table
Atomic weight is actually calculated by the sum of protons and neutrons of that atom. It is not equal to the number. You must add them for the result
Answer : The activation energy of the reaction is, 
Solution :
The relation between the rate constant the activation energy is,
![\log \frac{K_2}{K_1}=\frac{Ea}{2.303\times R}\times [\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7BK_2%7D%7BK_1%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= initial rate constant = 
= final rate constant = 
= initial temperature = 
= final temperature = 
R = gas constant = 8.314 kJ/moleK
Ea = activation energy
Now put all the given values in the above formula, we get the activation energy.
![\log \frac{8.75\times 10^{-3}L/mole\text{ s}}{4.55\times 10^{-5}L/mole\text{ s}}=\frac{Ea}{2.303\times (8.314kJ/moleK)}\times [\frac{1}{468K}-\frac{1}{531K}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7B8.75%5Ctimes%2010%5E%7B-3%7DL%2Fmole%5Ctext%7B%20s%7D%7D%7B4.55%5Ctimes%2010%5E%7B-5%7DL%2Fmole%5Ctext%7B%20s%7D%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20%288.314kJ%2FmoleK%29%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7B468K%7D-%5Cfrac%7B1%7D%7B531K%7D%5D)

Therefore, the activation energy of the reaction is, 