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andreyandreev [35.5K]
4 years ago
7

If 2.40 g of KNO3 reacts with sufficient sulfur (S8) and carbon (C), how much P-V work will the gases do against an external pre

ssure of 1.00 atm given the densities of nitrogen and carbon dioxide are 1.165 g/L and 1.830 g/L, respectively, at 20°C?
Physics
1 answer:
creativ13 [48]4 years ago
7 0

Answer:

-112.876J

Explanation:

In order to solve this question, we would need to incorporate Stoichiometry, which involves using relationships between reactants and/or products in a chemical reaction to determine desired quantitative data.

Here's a balanced equation for the reaction:

16KNO_3(s) + 24C(s) + S_8(s)    \to 24CO_2(g) + 8N_2(g) + 8K_2S(s)

Let us define P - V work as;

w_{pv} = - P_{external}  \triangle Volume

where  \triangle (Volume) = (V_{final} - V_{initial})

External pressure is given as  1.00atm , therefore the work solely depends on the change in volume and since the reactants are solids, none of the reactants contribute to the volume. Hence,  V_i = 0.

To find the volume of the products, we need to first find the amount of moles of the product made from  2.40_gKNO_3, using the molar mass of  KNO_3  which is 101.1032 g/mol  

2.40_gKNO_3 . {\frac{1molKNO_3}{101.1032_g}} = 0.0237molKNO_3

Now let us convert moles of  KNO_3  into moles of CO_2 and N_2  using the stoichiometric ratios from our balanced equation of the reaction.

0.0237molKNO_3 . {\frac{24molCO_2}{16molKNO_3}} = 0.0356molCO_2

0.0237molKNO_3 . {\frac{8molN_2}{16molKNO_3}} = 0.01185molN_2

K_2S is not factored into the volume calculation because it is a solid.

Now let us also convert the moles of  CO_2  and  N_2 into grams using their respective molar masses.

0.0356molCO_2 . {\frac{44.01_g}{1molCO_2}} = 1.567_gCO_2

0.01185molN_2 . {\frac{28.014_g}{1molN_2}} = 0.332_gN_2

We will now proceed to convert grams into volume using the density values provided.

1.567_gCO_2 . {\frac{1L}{1.830_g}} = 0.856LCO_2

0.332_gN_2 . {\frac{1L}{1.165_g}} = 0.285LN_2

Summing up the two volumes, we get the final volume

0.856L + 0.258L = 1.114L = V_f

Plugging everything into the w_{pv} equation, we get:

w_{pv} = -1atm(1.114L - 0L) = -1.114L.atm

Finally, let us convert L.atm into joules using the conversion rate of;

1L.atm = 101.325J\\-1.114L.atm. {\frac{101.325J}{1L.atm}} = -112.876J

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Answer:

21.35 cm^3

Explanation:

let the volume at the surface of fresh water is V.

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temperature remains constant.

density of water, d = 1000 kg/m^3

Pressure at the surface of fresh water is atmospheric pressure,

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5 0
3 years ago
A long metal cylinder with radius a is supported on an insulating stand on the axis of a long, hollow, metal tube with radius b.
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a)

i) Potential for r < a: V(r)=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

ii) Potential for a < r < b:  V(r)=\frac{\lambda}{2\pi \epsilon_0}  ln\frac{b}{r}

iii) Potential for r > b: V(r)=0

b) Potential difference between the two cylinders: V_{ab}=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

c) Electric field between the two cylinders: E=\frac{\lambda}{2\pi \epsilon_0} \frac{1}{r}

Explanation:

a)

Here we want to calculate the potential for r < a.

Before calculating the potential, we have to keep in mind that the electric field outside an infinite wire or an infinite cylinder uniformly charged is

E=\frac{\lambda}{2\pi \epsilon_0 r}

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By integration, we find an expression for the electric potential at a distance of r:

V(r) =\int Edr = \frac{\lambda}{2\pi \epsilon_0} ln(r)

Inside the cylinder, however, the electric field is zero, because the charge contained by the Gaussian surface is zero:

E=0

So the potential where the electric field is zero is constant:

V=const.

iii) We start by evaluating the potential in the region r > b. Here, the net electric field is zero, because the Gaussian surface of radius r here contains a positive charge density +\lambda and an equal negative charge density -\lambda. Therefore, the net charge is zero, so the electric field is zero.

This means that the electric potential is constant, so we can write:

\Delta V= V(r) - V(b) = 0\\\rightarrow V(r)=V(b)

However, we know that the potential at b is zero, so

V(r)=V(b)=0

ii) The electric field in the region a < r < b instead it is given only by the positive charge +\lambda distributed over the surface of the inner cylinder of radius a, therefore it is

E=\frac{\lambda}{2\pi r \epsilon_0}

And so the potential in this region is given by:

V(r)=\int\limits^b_r {Edr} = \frac{\lambda}{2\pi \epsilon_0}  (ln(b)-ln(r))=\frac{\lambda}{2\pi \epsilon_0}  ln\frac{b}{r} (1)

i) Finally, the electric field in the region r < a is zero, because the charge contained in this region is zero (we are inside the surface of the inner cylinder of radius a):

E = 0

This means that the potential in this region remains constant, and it is equal to the potential at the surface of the inner cylinder, so calculated at r = a, which can be calculated by substituting r = a into expression (1):

V(a)=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

And so, for r<a,

V(r)=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

b)

Here we want to calculate the potential difference between the surface of the inner cylinder and the surface of the outer cylinder.

We have:

- Potential at the surface of the inner cylinder:

V(a)=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

- Potential at the surface of the outer cylinder:

V(b)=0

Therefore, the potential difference is simply equal to

V_{ab}=V(a)-V(b)=\frac{\lambda}{2\pi \epsilon_0} ln(\frac{b}{a})

c)

Here we want to find the magnitude of the electric field between the two cylinders.

The expression for the electric potential between the cylinders is

V(r)=\int\limits^b_r {Edr} = \frac{\lambda}{2\pi \epsilon_0}  (ln(b)-ln(r))=\frac{\lambda}{2\pi \epsilon_0}  ln\frac{b}{r}

The electric field is just the derivative of the electric potential:

E=-\frac{dV}{dr}

so we can find it by integrating the expression for the electric potential. We find:

E=-\frac{d}{dr}(\frac{\lambda}{2\pi \epsilon_0} (ln(b)-ln(r))=\frac{\lambda}{2\pi \epsilon_0} \frac{1}{r}

So, this is the expression of the electric field between the two cylinders.

Learn more about electric fields:

brainly.com/question/8960054

brainly.com/question/4273177

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