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anastassius [24]
3 years ago
7

A combination of a heat engine driving a heat pump (see Fig. P7.106) takes waste energy at 50°C as a source Qw1 to the heat engi

ne rejecting heat at 30°C. The remainder Qw2 goes into the heat pump that delivers a QH at 150°C. If the total waste energy is 5 MW find the rate of energy delivered at the high temperature.
Chemistry
1 answer:
erma4kov [3.2K]3 years ago
7 0

Answer:

1.08 MW

Explanation:

Given that:

Heat supplied to heat engine

Q_{WS} = 5 MW

Temperature of the hot source of engine

T_{WS} = 323 K

Temperature of the cold source of engine

T_L = 303 K

the temperature and heat relation for a reversible heat engine can be presented as follows:

\frac{T_L}{T_{WS}} =\frac{Q_L}{Q_{WS}}

\frac{303}{323} =\frac{Q_L}{5}

Q_L = 4.69 MW

TO determine the work done by the heat engine ; we have:

W_{engine}=Q_{WS}-Q_{L}

W_{engine}=5 -4.69

W_{engine}=0.309MW

The temperature and heat relation for the reversible heat pump can be written as:

\frac{T_H}{T_L}=\frac{Q_H}{Q_L}

\frac{T_H}{T_L}=\frac{Q_H}{Q_H-W}

\frac{423}{303} =\frac{Q_H}{Q_H-W}

Q_H=1.396-0.309\\Q_H=1.08MW

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Q = Q(o) FT/FT(o) P(o)/P T/T(o)
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∴ Q = Q(o) FT/ FT(o) 
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                        = CA(o)((1-X)/(1+2X)) -----> eq 1
When K (the reaction rate constant) at 127C° can be evaluated with R (the gas constant)  8.314 J/mole.K° = 0.08205 L.atm/mole.°K

When, K2=K1(exp)[E/R ( (1/T1) - (1/T2)]
when T1 by kelvin = 50+273= 323 K° and T2= 127+273 = 400 K° 
and activition energy = 85 KJ/mol = 85000 J/mol
       ∴     K2   =10^-4 (exp) [85000/8314 ((1/323) - (1/400)] = 0.0443 min^-1 
We can get the concentration of (A) at 10 atm and 127C° (400K°) by:

CA(o)= PA(o) /RT = 10 / ( 0.08205 * 400 ) = 0.305 mol / L

∴ The reactor volume of the CSTR is:
V = FA(o)X / KCA---> eq 2 
by substitute eq 1 in eq 2
∴ V=[ FA(o)x * (1+2x)] / [ KCA(o) * (1-X) ] 
      = [ 2.5 * 0.9 * (1+1.8)] / [0.0443 * 0.305* 0.1]
     = 4662.7 L
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∴[ ( XCA(o) ) ( 2XCA(o)^2 ) ] / [ (1+2X)^2 * CA(o) * (1-X) ] = 0.025
 
when we have CA(o) (the initial concentration)= 0.305 mol/L, So we have this eq:
[(XCA(o)) (2XCA(o))^2] / [(1+2X)^2 CA(o) (1-X) ] = 0.025
 By the matlab function solve
∴ X= X eq = 0.512 for 90% of the equilibrium conversion
∴ X= 0.9 X eq =  0.4608




        





8 0
3 years ago
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