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nignag [31]
4 years ago
15

What is the concentration of a phosphoric acid solution of a 25.00 mL sample if the acid requires 42.24 mL of 0.135 M NaOH for n

eutralization?
Please explain your steps.
Chemistry
2 answers:
kaheart [24]4 years ago
8 0
0.0760 m

do this by:

finding the moles of NaOH which will be <span>5.702 E -3 m
</span>
next find the moles of H3PO4 which will be <span>1.90 E -3 m</span><span>
calulcate </span>25 ml sample molarity = 0.07603 m, just put 0.0760<span>

</span>
Leokris [45]4 years ago
4 0

Answer: The volume of 0.10 M NaOH required to neutralize 30 ml of 0.10 M HCl is, 30 ml.

Explanation:

According to the neutralization law,

n_1M_1V_1=n_2M_2V_2

where,

M_1 = molarity of NaOH solution = 0.135 M

V_1 = volume of NaOH solution = 42.24 ml

M_2 = molarity of H_3PO_4 solution = ?M

V_2 = volume of H_3PO_4 solution = 25 ml

n_1 = valency of NaOH = 1

n_2 = valency of H_3PO_4 = 3

1\times (0.135M)\times 42.24=3\times M_2\times 25

M_2=0.076M

Therefore, the concentration of 0.076 M of phosphoric acid of a 25 ml is required to neutralize 42.24 ml of 0.135 M NaOH.

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<u>Answer:</u> To calculate the pH of the buffer composed of H_2PO_4^-\text{ and }HPO_4^{-2}, we use the K_a2

<u>Explanation:</u>

Phosphoric acid is a triprotic acid and it will undergo three dissociation reaction each having their respective dissociation constants.

The chemical equation for the first dissociation reaction follows:

H_3PO_4\rightleftharpoons H_2PO_4^-+H^+;K_a1=6.9\times 10^{-3}

The chemical equation for the second dissociation reaction follows:

H_2PO_4^-\rightleftharpoons HPO_4^{2-}+H^+;K_a2=6.2\times 10^{-8}

The chemical equation for the third dissociation reaction follows:

HPO_4^{2-}\rightleftharpoons PO_4^{3-}+H^+;K_a3=4.8\times 10^{-13}

To form a buffer composed of H_2PO_4^-\text{ and }HPO_4^{-2}, we use the K_a of second dissociation process

To calculate the pK_a, we use the equation:

pK_a=-\log (K_a)\\\\pK_a=-\log(6.2\times 10^{-8})\\\\pK_a=7.21

To calculate the pH of buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a2+\log(\frac{[\text{conjugate base}]}{[\text{weak acid}]})

pH=pK_a2+\log(\frac{[HPO_4^{2-}]}{[H_2PO_4^-]})

We are given:

pK_a2 = negative logarithm of second acid dissociation constant of phosphoric acid = 7.21

[HPO_4^{2-}] = concentration of conjugate base

[H_2PO_4^{-}] = concentration of weak acid

Hence, to calculate the pH of the buffer composed of H_2PO_4^-\text{ and }HPO_4^{-2}, we use the K_a2

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