**Answer: n = 5, l = 3, ml =-3 does not contain an error.**

**Explanation:**

**Principle Quantum Numbers : **It describes the size of the orbital and the energy level. It is represented by n. Where, n = 1,2,3,4....

**Azimuthal Quantum Number : **It describes the shape of the orbital. It is represented as 'l'. The value of l ranges from 0 to (n-1). For l = 0,1,2,3... the orbitals are s, p, d, f...

**Magnetic Quantum Number :** It describes the orientation of the orbitals. It is represented as . The value of this quantum number ranges from . When l = 2, the value of will be -2, -1, 0, +1, +2.

1. For n = 4, l = 4, ml =0

n=4 and l can have value 0 to (n-1) i.e. 0,1 , 2 and 3 only. m can have 0, -1 , +1, -2, +2, -3 and +3 values. Thus l= +4 is not correct.

2. For n = 4, l = 0, ml =+1

n = 4 and l can have value 0 to (n-1) i.e. 0 , 1, 2 and 3 only. For l= 0 , m can have value of 0 only. Thus m= +1 is not correct.

3. For n = 5, l = 3, ml =-3

n=5 and l can have value 0 to (n-1) i.e. 0 ,1, 2 , 3 and 4 only. For l= 3 m can have 0, -1 ,+1, -2, +2, -3 ,+3 values.

4. For n = 3, l = 1, ml = +2

n=3 and l can have value 0 to (n-1) i.e. 0, 1 and 2 only. For l= 1, m can have 0, -1 ,+1 values. Thus m =+2 is not correct.

5. For n = 3, l = 2, ml =-3

n=3 and l can have value 0 to (n-1) i.e. 0 , 1 and 2. m can have 0, -1 ,+1, -2 and +2 values. Thus m= -3 is not correct.