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Ivahew [28]
3 years ago
13

The isomerization reaction, ch3nc → ch3cn, is first order and the rate constant is equal to 0.46 s-1 at 600 k. what is the conce

ntration of ch3nc after 0.20 minutes if the initial concentration is 0.30 m?
Chemistry
1 answer:
Harlamova29_29 [7]3 years ago
6 0
According to this formula :
㏑[A] /[Ao] = - Kt 
when we have Ao = 0.3 m 
and K =0.46 s^-1
t = 20min = 0.2 x 60 =12 s
So by substitution :
㏑[A] / 0.3 = - 0.46 * 12
㏑[A] / 0.3 = - 5.52
by taking e^x for both side of the equation we can get [A]
∴[A] = 0.0012 mol dm^-3
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kicyunya [14]

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The ΔH for the reaction is -456.5 KJ

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Here we want to determine ΔH for the reaction;

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ΔH = ΔH(product) - ΔH(reactant)

In the case of the first reaction;

ΔH = ΔH(CaO) + ΔH(CO2) - ΔH(CaCO3)  ...........................(*)

From the other reactions, we can get the respective ΔH for the individual molecule in the reaction

In second reaction;

Kindly note that for elements, molecule of gases, ΔH = 0

What this means is that throughout the solution;

ΔH(Ca)  = 0 KJ

ΔH(O2) = 0 KJ

ΔH(C) = 0 KJ

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ΔH = 2ΔH(CaCO3)

Thus;

-2414/2 = ΔH(CaCO3)

ΔH(CaCO3) = -1,207  KJ

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ΔH = ΔH(CO2)

Hence ΔH(CO2) = -393.5 KJ

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ΔH = ΔH(CaO)

Hence ΔH(CaO) = -1270 KJ

Going back to equation *

ΔH = ΔH(CaO) + ΔH(CO2) - ΔH(CaCO3)

Using the values of the ΔH  of the respective molecules given above,

ΔH  = -1270 + (-393.5) - (-1207)

ΔH  = -456.5 KJ

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