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Ivahew [28]
3 years ago
13

The isomerization reaction, ch3nc → ch3cn, is first order and the rate constant is equal to 0.46 s-1 at 600 k. what is the conce

ntration of ch3nc after 0.20 minutes if the initial concentration is 0.30 m?
Chemistry
1 answer:
Harlamova29_29 [7]3 years ago
6 0
According to this formula :
㏑[A] /[Ao] = - Kt 
when we have Ao = 0.3 m 
and K =0.46 s^-1
t = 20min = 0.2 x 60 =12 s
So by substitution :
㏑[A] / 0.3 = - 0.46 * 12
㏑[A] / 0.3 = - 5.52
by taking e^x for both side of the equation we can get [A]
∴[A] = 0.0012 mol dm^-3
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A chemist wants to extract copper metal from copper chloride solution. The chemist places 0.50 grams of aluminum foil in a solut
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Answer:

Approximately 0.36 grams, because copper (II) chloride acts as a limiting reactant.

Explanation:

  • It is a stichiometry problem.
  • We should write the balance equation of the mentioned chemical reaction:

<em>2Al + 3CuCl₂ → 3Cu + 2AlCl₃.</em>

  • It is clear that 2.0 moles of Al foil reacts with 3.0 moles of CuCl₂ to produce 3.0 moles of Cu metal and 2.0 moles of AlCl₃.
  • Also, we need to calculate the number of moles of the reported masses of Al foil (0.50 g) and CuCl₂ (0.75 g) using the relation:

<em>n = mass / molar mass</em>

  • The no. of moles of Al foil = mass / atomic mass = (0.50 g) / (26.98 g/mol) = 0.0185 mol.
  • The no. of moles of CuCl₂ = mass / molar mass = (0.75 g) / (134.45 g/mol) = 5.578 x 10⁻³  mol.
  • <em>From the stichiometry Al foil reacts with CuCl₂ with a ratio of 2:3.</em>

∴ 3.85 x 10⁻³  mol of Al foil reacts completely with 5.578 x 10⁻³  mol of CuCl₂ with <em>(2:3)</em> ratio and CuCl₂ is the limiting reactant while Al foil is in excess.

  • From the stichiometry 3.0 moles of  CuCl₂ will produce the same no. of moles of copper metal (3.0 moles).
  • So, this reaction will produce 5.578 x 10⁻³ mol of copper metal.
  • Finally, we can calculate the mass of copper produced using:

mass of Cu = no. of moles x Atomic mass of Cu = (5.578 x 10⁻³  mol)(63.546 g/mol) = 0.354459 g ≅ 0.36 g.

  • <u><em>So, the answer is:</em></u>

<em>Approximately 0.36 grams, because copper (II) chloride acts as a limiting reactant.</em>

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