Answer:
(b)Distortion energy theory.
Explanation:
The best suitable theory for ductile material:
(1)Maximum shear stress theory (Guest and Tresca theory)
It theory state that applied maximum shear stress should be less or equal to its maximum shear strength.
(2)Maximum distortion energy theory(Von Mises henkey's theory)
It states that maximum shear train energy per unit volume at any point is equal to strain energy per unit volume under the state of uni axial stress condition.
But from these two Best theories ,suitable theory is distortion energy theory ,because it gives best suitable result for ductile material.
Answer:
|W|=169.28 KJ/kg
ΔS = -0.544 KJ/Kg.K
Explanation:
Given that
T= 100°F
We know that
1 °F = 255.92 K
100°F = 310 .92 K
We know that work for isothermal process
Lets take mass is 1 kg.
So work per unit mass
We know that for air R=0.287KJ/kg.K
W= - 169.28 KJ/kg
Negative sign indicates compression
|W|=169.28 KJ/kg
We know that change in entropy at constant volume
ΔS = -0.544 KJ/Kg.K
Answer:
Explained
Explanation:
In the experiment, an (18)O-labelled alcohol R('18)OH is used with normal unlabeled carboxylic acid RC(16)O2H:
The esterification reaction is:
(note: the bracketed values are atomic masses)
RC(16)O_2H + R'(18)OH => RC16O18OR' + H_2(16)O
Since the alcohol is the nucleophile in this nucleophilic substitution reaction, it adds to the carbonyl group of the carboxylic acid and the (18)O atom becomes incorporated into the ester product, while the (16)OH group of the carboxylic acid is expelled as H_2(16)O.
By using mass spectroscopy to measure the mass of the ester and water products, it can be shown that each ester molecule contains one (18)O atom and one (16)O atom, while the water molecules contains only (16)O atoms.
This would prove unequivocally that the ester contains one O atom from the carboxylic acid and one O atom from the alcohol, while the water contains only O atoms from the carboxylic acid.
