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natta225 [31]
3 years ago
6

A mixture of 0.10 mol of NO, 0.050 mol of H2, and 0.10 mol of H2O is placed in a 1.0- L vessel at 300 K . The following equilibr

ium is established:
2NO(g)+2H2(g)--->/<---N2(g)+2H2O(g)

At equilibrium [NO]=0.062M

Calculate the equilibrium concentration of N2.
Chemistry
1 answer:
umka2103 [35]3 years ago
5 0

Answer:

The concentration of N2 at the equilibrium will be 0.019 M

Explanation:

Step 1: Data given

Number of moles of NO = 0.10 mol

Number of moles of H2 = 0.050 mol

Number of moles of H2O = 0.10 mol

Volume = 1.0 L

Temperature = 300K

At equilibrium [NO]=0.062M

Step 2: The balanced equation

2NO(g) + 2H2(g) → N2(g) + 2H2O(g)

Step 3: Calculate the initial concentration

Concentration = Moles / volume

[NO] = 0.10 mol / 1L = 0.10 M

[H2] = 0.050 mol / 1L = 0.050 M

[H2O] = 0.10 mol / 1L = 0.10 M

[N2] = 0 M

Step 4: Calculate the concentration at the equilibrium

[NO] at the equilibrium is 0.062 M

This means there reacted 0.038 mol (0.038M) of NO

For 2 moles NO we need 2 moles of H2 to produce 1 mol N2 and 2 moles of H2O

This means there will also react 0.038 mol of H2

The concentration at the equilibrium is 0.050 - 0.038 = 0.012 M

There will be porduced 0.038 moles of H2O, this means the final concentration pf H2O at the equilibrium is 0.100 + 0.038 = 0.138 M

There will be produced 0.038/2 = 0.019 moles of N2

The concentration of N2 at the equilibrium will be 0.019 M

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In the given question, the charging of a storage battery using electric current is an example of electrical energy being converted into chemical energy.  


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Rank the following elements by effective nuclear charge, Zeff, for a valence electron. F LI Be B N
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Answer:

Rank in increasing order of effective nuclear charge:

  • Li < Be < B < N < F

Explanation:

This explains the meaning of effective nuclear charge, Zeff, how to determine it, and the calculations for a valence electron of each of the five given elements: F, Li, Be, B, and N.

<u>1) Effective nuclear charge definitions</u>

  • While the total positive charge of the atom nucleus (Z) is equal to the number of protons, the electrons farther away from the nucleus experience an effective nuclear charge (Zeff) less than the total nuclear charge, due to the fact that electrons in between the nucleus and the outer electrons partially cancel the atraction from the nucleus.

  • Such effect on on a valence electron is estimated as the atomic number less the number of electrons closer to the nucleus than the electron whose effective nuclear charge is being determined: Zeff = Z - S.

<u><em>2) Z eff for a F valence electron:</em></u>

  • F's atomic number: Z = 9
  • Total number of electrons: 9 (same numer of protons)
  • Period: 17 (search in the periodic table or do the electron configuration)
  • Number of valence electrons:  7 (equal to the last digit of the period's number)
  • Number of electrons closer to the nucleus than a valence electron: S = 9 - 7 = 2
  • Zeff = Z - S = 9 - 2 = 7

<u><em>3) Z eff for a Li valence eletron:</em></u>

  • Li's atomic number: Z = 3
  • Total number of electrons: 3 (same number of protons)
  • Period: 1 (search on the periodic table or do the electron configuration)
  • Number of valence electrons: 1 (equal to the last digit of the period's number)
  • Number of electrons closer to the nucleus than a valence electron: S = 3 - 1 = 2
  • Z eff = Z - S = 3 - 2 = 1.

<em>4) Z eff for a Be valence eletron:</em>

  • Be's atomic number: Z = 4
  • Total number of electrons: 4 (same number of protons)
  • Period: 2 (search on the periodic table or do the electron configuration)
  • Number of valence electrons: 2 (equal to the last digit of the period's number)
  • Number of electrons closer to the nucleus than a valence electron: S = 4 - 2 = 2
  • Z eff = Z - S = 4 - 2 = 2

<u><em>5) Z eff for a B valence eletron:</em></u>

  • B's atomic number: Z = 5
  • Total number of electrons: 5 (same number of protons)
  • Period: 13 (search on the periodic table or do the electron configuration)
  • Number of valence electrons: 3 (equal to the last digit of the period's number)
  • Number of electrons closer to the nucleus than a valence electron: S = 5 - 3 = 2
  • Z eff = Z - S = 5 - 2 = 3

<u><em>6) Z eff for a N valence eletron:</em></u>

  • N's atomic number: Z = 7
  • Total number of electrons: 7 (same number of protons)
  • Period: 15 (search on the periodic table or do the electron configuration)
  • Number of valence electrons: 5 (equal to the last digit of the period's number)
  • Number of electrons closer to the nucleus than a valence electron: S = 7 - 5 = 2
  • Z eff = Z - S = 7 - 2 = 5

<u><em>7) Summary (order):</em></u>

  Atom          Zeff for a valence electron

  • F                   7
  • Li                   1
  • Be                 2
  • B                   3
  • N                   5

  • <u>Conclusion</u>: the order is Li < Be < B < N < F
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Answer:

H+ ( aq ) + HCO3- ( aq ) ------> H2O( l ) + CO2 ( g )

Explanation:

The complete reaction when hydroiodic acid and sodium hydrogen carbonate combine, would be as follows -

HI + NaHCO3 ----> NaI + H2O + CO2

net reaction

H2CO3 is highly unstable, and thus decomposes into the water and carbon dioxide you see present as the reactants. If you didn't know already, H2CO3 is also reffered to as carbonic acid. The rest of the elements present on the reactant side are Iodine and Sodium, which is why they are present on the product side as NaI.

Let me include the " physical states " in this reaction as well -

HI ( aq ) + NaHCO3 ( aq ) ----> NaI ( aq ) + H2O ( l ) + CO2 ( g )

Now the complete ionic equation would simply be each compound present as ions in an aqueous solution, so there is no need for an explanation on this step -

H+ ( aq ) + I- ( aq ) + Na+ ( aq ) + HCO3- ( aq ) -------> Na+ ( aq ) + I- ( aq ) + H2O( l ) + CO2 ( g )

The spectator ions in this reaction are I- and Na+, so canceling them out, you would receive the following net ionic equation -

H+ ( aq ) + HCO3- ( aq ) ------> H2O( l ) + CO2 ( g )

<u><em>Hope that helps!</em></u>

4 0
3 years ago
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