Answer:
See explanation
Explanation:
The reaction between tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate as well as the reaction of tetraphenylcyclopentadienone and diphenylacetylene are Diels Alder reactions. The former is performed in presence of a solvent while the former is performed neat.
The reaction of tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate leads to the formation of a more resonance-stabilized aromatic ring(lower energy product) compared to the reaction of tetraphenylcyclopentadienone and diphenylacetylene.
Hence, the reaction between tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate can be conducted at relatively lower temperature compared to the reaction between tetraphenylcyclopentadienone and diphenylacetylene.
Contains only Carbon and Hydrogen.
(3) CH3CH3
Answer:
Kc = 168.0749
Explanation:
initial mol: 0.822 0 0
equil. mol: 2(0.822 - x) x x
∴ [ HI ]eq = 0.055 mol/L = 2(0.822 - x) / (1.11 L )
⇒ 1.644 - 2x = 0.055 * 1.11
⇒ 1.644 = 2x + 0.06105
⇒ 2x = 1.583
⇒ x = 0.7915 mol equilibrium
⇒ [ H2 ] eq = 0.7915mol / 1.11L = 0.7130 M = [ I2 ] eq
⇒ Kc = ([ H2 ] * [ I2 ]) / [ HI ]²
⇒ Kc = ( 0.7130² ) / ( 0.055² )
⇒ Kc = 168.0749
I think the volume should be still 14.3L. In this question, the gas is being held in a tank. The tank has a constant volume. The gas in the tank has the property to fill the space. So when the temperature changes, the pressure changes too. But the volume doesn't change.
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