What greek letter are used in the precise definition of a limit?
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If the concentration of acetyl chloride is increased ten times the rate of reaction is increased ten times.
The conversion of acetyl chloride to methyl acetate is a substitution reaction. Recall that a substitution reaction is one in which a moiety in a molecule is replaced by another.
In this reaction, the CH3O- ion replaces the chloride ion. In the first step, the CH3O- ion attacks the substrate in a slow step. This creates a tetrahedral intermediate. Loss of the chloride ion yields the methyl acetate product.
The rate determining step is the formation of the tetrahedral intermediate. Since the reaction is first order in the acetyl chloride, if its concentration is increased ten times the rate of reaction is increased ten times.
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Answer:
a. A reaction in which the entropy of the system increases can be spontaneous only if it is endothermic.
Explanation:
The change in free energy (ΔG) that is, the <u>energy available to do work</u>, of a system for a constant-temperature process is:
- When ΔG < 0 the reaction is spontaneous in the forward direction.
- When ΔG > 0 the reaction is nonspontaneous. The reaction is
spontaneous in the opposite direction.
- When ΔG = 0 the system is at equilibrium.
If <u>both ΔH and ΔS are positive</u>, then ΔG will be negative only when the TΔS term is greater in magnitude than ΔH. This condition is met when T is large.