Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
Answer:
0.158 moles KMnO4
Explanation:
According to the Periodic Table,
K = 39.10 g/mol
Mn = 54.94 g/mol
O = 16.00 g/mol
KMnO4 = 39.10 g/mol + 54.94 g/mol + 4(16.00 g/mol) = 158.04 g/mol
25.0 grams KMnO4 1 mole
----------------------------- x -------------------------- = 0.158 moles KMnO4
158.04 grams
B positive and negative ion
Answer: option D is right.
Explanation: There are four types of fundamental forces in nature.These are named as gravitational force,electromagnetic force,strong nuclear force and weak nuclear force.
As per the question we have to understand the role of strong nuclear force and weak nuclear force.
An atom consists of a nucleus surrounded by extra nuclear part consisting of electrons in various orbits.The nucleus contains two basic particles called protons and neutrons .Protons are positively charged while neutrons are neutral.Protons being positively charged will impart repulsive force on each other and may come out of the nucleus.But the nucleus is stable.That is due to the strong nuclear force.
Strong nuclear force is a spin dependent and charge independent force which comes into existence due to the mutual interaction of gluons which binds the protons and neutrons .Hence it is attractive in nature.It's 100 times more stronger than electromagnetic force also.
Weak nuclear force comes into existence during radio -active decay .This force is due to the exchange of ' w' and 'z' bosons[the particles like protons and neutrons having integral or zero spin] which are heavier in nature.The role of it is to change protons into neutrons and vice versa.Its a short range force.
Hence the option D is right.
