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⭐ Elements in which the last electron enters any one of the five d-oribitals of their respective penultimate shells are called as <u>d-block</u><u> </u><u>elem</u><u>ents</u> .
⭐ But the last electron of Zn , Cd , Hg and Cn enters in the s-oribital of their respective ultimate shells rather than the d-oribitals of their respective penultimate shells . Therefore, these elements cannot be regarded as d-block elements .
☃️ But properties of these elements resemble to the d-block elements rather than s-block elements .
☃️ Therefore, to make the study of periodic classification of elements more rational, they are studied along with d-block elements .
✍️ Thus <u>on the basis of properties</u> all transition elements are d- block elements, but <u>on the basis of electronic configuration</u> all d -block elements are not transition elements .
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Answer: The pH will be 3.87
Explanation:
pH or pOH is the measure of acidity or alkalinity of a solution.
pH is calculated by taking negative logarithm of hydrogen ion concentration.
According to stoichiometry,
1 mole of gives 1 mole of
Thus moles of
gives =
moles of
Putting in the values:
Thus the pH will be 3.87
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
A solution is prepared by dissolving biphenyl into naphthalene. We can calculate the freezing point depression (ΔT) for naphthalene using the following expression.
where,
- i: van 't Hoff factor (1 for non-electrolytes)
- Kf: cryoscopic constant
- m: molality
The normal freezing point of naphthalene is 80.26 °C. The freezing point of the solution is:
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
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