Explanation:
Method of prepration of sodium thiosulphate - definition
In the laboratory, this salt can be prepared by heating an aqueous solution of sodium sulphite with sulphur or by boiling aqueous NaOH and sulfur according to this equation:

Answer:
If the question is which can make a buffer, then NH3, NH4Cl should be correct. Because Ammonium (NH4) is conjugate acid of NH3 so they can form an equilibrium which is basically a buffer whose purpose is to resist pH change.
Explanation:
It has to be D. the time needed to boil the water decreased