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maw [93]
3 years ago
9

3. When two atoms of 2H (deuterium) are fused to form one atom of 4He (helium), the total energy evolved is 3.83 × 10-12 joules.

What is the total change in mass (in kilograms) for this reaction?
4. The mass of a proton is 1.00728 atomic mass units (amu) and the mass of a neutron is
60Co nucleus whose nuclear mass is 1.00867 amu. What is the mass defect (in amu) of a 27
59.9338 amu? What is the mass defect in kilograms? What is the energy equivalent of this mass in kilojoules?
5. The equation shows one mole of ethanol fuel being burned in oxygen. Convert the energy released into its equivalent mass.
C2H5OH(l) + 3 O2(g)  2 CO2(g) + 3 H2O (l) ΔH = -1418 kJ/mol
Chemistry
2 answers:
balandron [24]3 years ago
6 0
3.
∆E = ∆m x c ² ∆m = E / c ² ∆m = 3,83•10^-12 / 3•10^8 ² ∆m = 4,256•10^-29 kg

Taking this class as well 
matrenka [14]3 years ago
6 0

<u>Answer:</u>

<u>For 3:</u> The total mass change of the reaction is 4.255\times 10^{3}kg

<u>For 4:</u> The mass defect is 0.911\times 10^{-27}kg and energy equivalent to this mass is 8.199\times 10^{-14}kJ

<u>For 5:</u> The equivalent mass of the reaction is 1.5755\times 10^{-11}kg

<u>Explanation:</u>

  • <u>For 3:</u>

To calculate the mass change of the reaction for given energy released, we use Einstein's equation:

E=\Delta mc^2

E = Energy released = 3.83\times 10^{-12}J

\Delta m = mass change = ?

c = speed of light = 3\times 10^8m/s

Putting values in above equation, we get:

3.83\times 10^{-12}Kgm^2/s^2=\Delta m\times (3\times 10^8m/s)^2\\\\\Delta m=4.255\times 10^3kg

Hence, the total mass change of the reaction is 4.255\times 10^{3}kg

  • <u>For 4:</u>

For the given isotopic representation:  _{27}^{60}\textrm{Co}

Atomic number = Number of protons = 27

Mass number = 60

Number of neutrons = Mass number - Atomic number = 60 - 27 = 33

To calculate the mass defect of the nucleus, we use the equation:

\Delta m=[(n_p\times m_p)+(n_n\times m_n)+]-M

where,

n_p = number of protons  = 27

m_p = mass of one proton  = 1.00728 amu

n_n = number of neutrons  = 33

m_n = mass of one neutron = 1.00867 amu

M = Nuclear mass number = 59.9338 amu

Putting values in above equation, we get:

\Delta m=[(27\times 1.00728)+(33\times 1.00867)]-[59.9338]\\\\\Delta m=0.54887amu

Converting the value of amu into kilograms, we use the conversion factor:

1amu=1.66\times 10^{-27}kg

So, 0.54887amu=0.54887\times 1.66\times 10^{-27}kg=0.911\times 10^{-27}kg

To calculate the equivalent energy, we use the equation:

E=\Delta mc^2

E = Energy released = ?

\Delta m = mass change = 0.911\times 10^{-27}kg

c = speed of light = 3\times 10^8m/s

Putting values in above equation, we get:

E=(0.911\times 10^{-27}kg)\times (3\times 10^8m/s)^2\\\\E=8.199\times 10^{-11}J

Converting this into kilojoules, we use the conversion factor:

1 kJ = 1000 J

So, 8.199\times 10^{-11}J=8.199\times 10^{-14}kJ

Hence, the mass defect is 0.911\times 10^{-27}kg and energy equivalent to this mass is 8.199\times 10^{-14}kJ

  • <u>For 5:</u>

For the given chemical reaction:

C_2H_5OH(l)+3O_2(g)\rightarrow 2CO_2(g)+3H_2O(l);\Delta H=-1418kJ/mol

To calculate the equivalent mass of the reaction for given energy released, we use Einstein's equation:

E=\Delta mc^2

E = Energy released = 1418kJ=1418\times 10^3J

\Delta m = mass change = ?

c = speed of light = 3\times 10^8m/s

Putting values in above equation, we get:

1418\times 10^{3}Kgm^2/s^2=\Delta m\times (3\times 10^8m/s)^2\\\\\Delta m=1.5755\times 10^{-11}kg

Hence, the equivalent mass of the reaction is 1.5755\times 10^{-11}kg

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Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th
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Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

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The mixture would contain

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Construct a RICE table for the hydrolysis of \text{Ac}^{-} under a basic aqueous environment (with a negligible hydronium concentration.)

\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}

The question supplied the <em>acid</em> dissociation constant pK_afor acetic acid \text{HAc}; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant pK_b for its conjugate base, \text{Ac}^{-}. The following relationship relates the two quantities:

pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})

... where the water self-ionization constant pK_w \approx 14 under standard conditions. Thus pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3. By the definition of pK_b:

[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b =  10^{-pK_{b}}

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