Answer:
The boiling point is 308.27 K (35.27°C)
Explanation:
The chemical reaction for the boiling of titanium tetrachloride is shown below:
Ti
⇒ Ti
ΔH°
(Ti) = -804.2 kJ/mol
ΔH° (Ti) = -763.2 kJ/mol
Therefore,
ΔH° = ΔH° (Ti) - ΔH° (Ti) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol
Similarly,
s°(Ti) = 221.9 J/(mol*K)
s°(Ti) = 354.9 J/(mol*K)
Therefore,
s° = s° (Ti) - s°(Ti) = 354.9 - 221.9 = 133 J/(mol*K)
Thus, T = ΔH° /s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C
Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.
A gem is a crystalized mineral.
Answer:
- <u>Tellurium (Te) and iodine (I) are two elements </u><em><u>next to each other that have decreasing atomic masses.</u></em>
Explanation:
The <em>atomic mass</em> of tellurium (Te) is 127.60 g/mol and the atomic mass of iodine (I) is 126.904 g/mol; so, in spite of iodine being to the right of tellurium in the periodic table (because the atomic number of iodine is bigger than the atomic number of tellurium), the atomic mass of iodine is less than the atomic mass of tellurium.
The elements are arranged in increasing order of atomic number in the periodic table.
The atomic number is equal to the number of protons and the mass number is the sum of the protons and neutrons.
The mass number, except for the mass defect, represents the atomic mass of a particular isotope. But the atomic mass of an element is the weighted average of the atomic masses of the different natural isotopes of the element.
Normally, as the atomic number increases, you find that the atomic mass increases, so most of the elements in the periodic table, which as said are arranged in icreasing atomic number order, match with increasing atomic masses. But the relative isotope abundaces of the elements can change that.
It is the case that the most common isotopes of tellurium have atomic masses 128 amu and 130 amu, whilst most common isotopes of iodine have an atomic mass 127 amu. As result, tellurium has an average atomic mass of 127.60 g/mol whilst iodine has an average atomic mass of 126.904 g/mol.
<h2>Heptene formed is -</h2><h2>
</h2>
Explanation:
The two possibilities when the peroxide is not present
+ HBr →
In presence peroxide,
≡
+ HBr →
- When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
- This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
- One mole of HBr adds to one mole of 1-heptane.
- The structure of heptene formed is -
