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beks73 [17]
3 years ago
14

Calculate the equilibrium constant for the reaction between fe2+(aq) and zn(s) under standard conditions at 25∘c.

Chemistry
1 answer:
Hatshy [7]3 years ago
7 0
Following reaction occurs in the given electrochemical system:
Fe^{2+} + Zn → Fe + Zn^{2+}
Thus, under standard conditions
E(0) = E(0) Fe2+/Fe - E(0) Zn2+/Zn
where, E^{0}Fe2+/Fe = standard reduction potential of Fe2+/Fe = -0.44 v
E^{0}Zn2+/Zn = standard reduction potential of Zn2+/Zn = -0.763 v

E(0) = 0.323 v
now, we know that, ΔG(0) =-nFE(0) ............... (1)
Also, ΔG^{0} = -RTln(K) ............ (2)

On equating and rearranging equation 1 and 2, we get
K = exp( \frac{nFE(0)}{RT} )= exp (\frac{2X96500X0.323}{8.314X298}) = 8.46 x 10^{10}

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