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Hatshy [7]
2 years ago
5

Explain why a solution that is 1.3 M HF and 1.3 mM KF is not a good buffer. HF is a strong acid and cannot be used in a buffer s

ystem. The ratio of acid to conjugate base is outside the buffer range of 10:1. The two species are not a conjugate acid base pair. KF is not soluble in water and cannot be used in a buffer system.
Chemistry
1 answer:
zavuch27 [327]2 years ago
4 0

Answer:

The ratio of acid to conjugate base is outside the buffer range of 10:1.

Explanation:

The Henderson-Hasselbalch equation for a buffer is

\text{pH} = \text{pK}_{\text{a}} + \log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}}

A buffer should have

\dfrac{1}{10} \leq \dfrac{\text{[A$^{-}]$}}{\text{[HA]}} \leq \dfrac{10}{1}

For a solution that is 1.3 mol·L⁻¹ in HF and 1.3 mmol·L⁻¹ in KF, the ratio is

\dfrac{1.3 \times 10^{-3} }{1.3} = \dfrac{1}{1000}

The ratio of acid to conjugate base is 1000:1, which is outside the range of 10:1.

A is wrong. NF is a weak acid.

C is wrong. The two species are a conjugate acid-base pair.

D is wrong. Salts of Group 1 metals are soluble.

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3 years ago
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A container has a volume of 2.79 L and a pressure of 5.97 atm. If the pressure changes to 1460 mm Hg, what is the container’s ne
maw [93]

Answer:

8.68 L is the new volume

Explanation:

You use Boyle's law for this.

P_{1}V_{1}=P_{2}V_{2}

P_{1} = first pressure

P_{2} = second pressure

V_{1} = first volume

V_{2} = second volume

Convert pressure from atm to mmHg (use same units):

5.97 x 760 = 4537.2 -> 4.54 x 10³

...maintain 3 significant figures in calculation, and round as needed...

(4.54 x 10³ mmHg)(2.79 L) = (1460 mmHg)(V_{2})

(4.54 x 10³ mmHg)(2.79 L) / (1460 mmHg) = V_{2} = 8.68 L

Hope this helps :)

5 0
2 years ago
Identify all statements that accurately describe the structure of the pyruvate dehydrogenase ( PDH ) complex.
Nostrana [21]

Answer:

The statements that correctly describes pyruvate dehydrogenase includes:

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-E 2 contains three domains.

Explanation:

Pyruvate dehydrogenase is a hydrolase key enzyme in glucose metabolism which converts pyruvate to acetyl- ChoA. It also forms a complex that catalyzes an irreversible reaction that is the entry point of pyruvate into the TCA cycle. Pyruvate dehydrogenase complex contains E1, E2 and E3 enzymes that transform pyruvate, NAD+, coenzyme A into acetyl-CoA, CO2, and NADH. Also, A regulatory kinase and phosphatase are part of the mammalian PDH complex and E 2 contains three domains.

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Answer:

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Explanation:

The dry atmosphere is composed almost entirely of nitrogen (in a volumetric mixing ratio of 78.1%) and oxygen (20.9%), plus a series of oligogases such as argon (0.93%), helium and gases of greenhouse effect such as carbon dioxide (0.035%) and ozone. In addition, the atmosphere contains water vapor in very variable amounts (about 1%) and aerosols.

Greenhouse gases or greenhouse gases are the gaseous components of the atmosphere, both natural and anthropogenic, that absorb and emit radiation at certain wavelengths of the infrared radiation spectrum emitted by the Earth's surface, the atmosphere and clouds . In the Earth's atmosphere, the main greenhouse gases (GHG) are water vapor (H2O), carbon dioxide (CO2), nitrous oxide (N2O), methane (CH4) and ozone (O3 ). There is also in the atmosphere a series of greenhouse gases (GHG) created entirely by humans, such as halocarbons (compounds containing chlorine, bromine or fluorine and carbon, these compounds can act as potent greenhouse gases in the atmosphere and they are also one of the causes of the depletion of the ozone layer in the atmosphere) regulated by the Montreal Protocol. In addition to CO2, N2O and CH4, the Kyoto Protocol sets standards regarding sulfur hexafluoride (SF6), hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs).

The difference between argon and greenhouse gases such as CO2 is that the individual atoms in the argon do not have free bonds and therefore do not vibrate. As a consequence, it does not reach a state of vibrational excitation when infrared radiation strikes this gas.

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3 years ago
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