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Maru [420]
2 years ago
10

A 25.00-ml sample of propionic acid, hc3h5o2, of unknown concentration was titrated with 0.141 m koh. the equivalence point was

reached when 37.48 ml of base had been added. what is the concentration of the propionate ion at the equivalence point?
a. 0.211 m
b. 0.147 m
c. 0.141 m
d. 0.0846 m
e. 0.128 m
Chemistry
1 answer:
Scorpion4ik [409]2 years ago
7 0
 The concentration of propionate ions   at  equivalent point is  0. 084 M
  calculation
write the equation for reaction
HC3H5O2   +  KOH  → H2O  + KC3H5O2

find the moles  of  KOH  used
moles=  molarity  × volume in liters
volume  in liters = 37.48 ml/1000 =0.03718L
molarity = 0.141 M


moles is therefore =  0.141 M  x0.03718 =  5.24238  x10^-3 moles

by use of mole  ratio between  KOH  and K3C3H5O2  which is 1:1  the  moles of K3C3H5O2  is also = 5.24238 x10^-3  moles

molarity is therefore = number  of moles/volume in liters
volume  in liters = 25/1000 +37.48/1000=0.06248 L

molarity of  propionate ions is therefore = (5.24238 x10^-3) / 0.06248 = 0.084  M
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Answer:

Explanation:

Cu:

Number of moles = Mass / molar masa

2 mol = mass / 64 g/mol

Mass = 128 g

Mg:

Number of moles = Mass / molar masa

0.5 mol = mass / 24 g/mol

Mass =  g

Cl₂:

Number of moles = Mass / molar masa

Number of moles  = 35.5 g / 24 g/mol

Number of moles = 852 mol

H₂:

Number of moles = Mass / molar mass

8 mol  = Mass / 2 g/mol

Mass =  16 g

P₄:

Number of moles = Mass / molar masa

2 mol  =  mass / 124 g/mol

Mass = 248 g

O₃:

Number of moles = Mass / molar masa

Number of moles  = 1.6 g /48  g/mol

Number of moles = 0.033 mol

H₂O

Number of moles = Mass / molar masa

Number of moles  = 54 g / 18 g/mol

Number of moles = 3 mol

CO₂

Number of moles = Mass / molar masa

2 mol  =  mass / 124 g/mol

Mass = 248 g

NH₃

Number of moles = Mass / molar masa

Number of moles  = 8.5 g / 17 g/mol

Number of moles = 0.5 mol

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Number of moles = Mass / molar masa

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Number of moles = 1 mol

a)

Given data:

Mass of iron(III)oxide needed = ?

Mass of iron produced = 100 g

Solution:

Chemical equation:

F₂O₃ + 3CO    →    2Fe  + 3CO₂

Number of moles of iron:

Number of moles = mass/ molar mass

Number of moles = 100 g/ 56 g/mol

Number of moles = 1.78 mol

Now we compare the moles of iron with iron oxide.

                        Fe          :           F₂O₃                

                           2          :             1

                          1.78       :        1/2×1.78 = 0.89 mol

Mass of  F₂O₃:

Mass = number of moles × molar mass

Mass = 0.89 mol × 159.69 g/mol

Mass = 142.124 g

100 g of iron is 1.78 moles of Fe, so 0.89 moles of F₂O₃ are needed, or 142.124 g of iron(III) oxide.

b)

Given data:

Number of moles of Al = 0.05 mol

Mass of iodine = 26 g

Limiting reactant = ?

Solution:

Chemical equation:

2Al + 3I₂   →  2AlI₃

Number of moles of iodine = 26 g/ 254 g/mol

Number of moles of iodine = 0.1 mol

Now we will compare the moles of Al and I₂ with AlI₃.

                          Al            :         AlI₃    

                          2             :           2

                         0.05         :        0.05

                           I₂            :         AlI₃

                           3            :          2

                         0.1           :           2/3×0.1 = 0.067

Number of moles of AlI₃ produced by Al are less so it will limiting reactant.

Mass of AlI₃:                            

Mass = number of moles × molar mass

Mass = 0.05 mol × 408 g/mol

Mass = 20.4 g

26 g of iodine is 0.1 moles. From the equation, this will react with 2 moles of Al. So the limiting reactant is Al.

c)

Given data:

Mass of lead = 6.21 g

Mass of lead oxide = 6.85 g

Equation of reaction = ?

Solution:

Chemical equation:

2Pb + O₂   → 2PbO

Number of moles of lead = mass / molar mass

Number of moles = 6.21 g/ 207 g/mol

Number of moles = 0.03 mol

Number of moles of lead oxide = mass / molar mass

Number of moles = 6.85 g/ 223 g/mol

Number of moles = 0.031 mol

Now we will compare the moles of oxygen with lead and lead oxide.

               Pb         :        O₂

                2          :         1

               0.03     :      1/2×0.03 = 0.015 mol

Mass of oxygen:

Mass = number of moles × molar mass

Mass = 0.015 mol × 32 g/mol

Mass =  0.48 g

The mass of oxygen that took part in equation was 0.48 g. which is 0.015 moles of oxygen. The number of moles of Pb in 6.21 g of lead is 0.03 moles. So the balance equation is

2Pb + O₂   → 2PbO

   

6 0
2 years ago
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