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2 years ago

Given: h2o(aq) + h2o(l) h3o+(aq) + oh–(aq) δh°rxn > 0 when the temperature of a sample of pure water is raised above 25°c,

1 answer:

7 0

When Δ H > 0 that means this is an endothermic reaction, and we can assume heat as one of the reactants. SO when the temperature increases so the reaction will move rightward to decrease the reactants and increase the products and as the products increase it will make the Kw increase also as
Kw = [Products] /[reactants].

So our answer will be: the value of Kw will increase.

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Look at the questions below and decide which is declarative.

Yuliya22 [10]

Im not sure but here is some information to help A declarative question is a yes-no question that has the form of a declarative sentence but is spoken with rising intonation at the end. Declarative sentences are commonly used in informal speech to express surprise or ask for verification.

3 0

3 years ago

Ethanol (C2H5OH) melts a - 144 oC and boils at 78 °C. The enthalpy of fusion of ethanol is 5.02 kj/mol, and its enthalpy of vapo

hammer [34]

Answer:

For a: The total heat required is 36621.5 J

For b: The total heat required is 58944.5 J

Explanation:

For a:

To calculate the heat required at different temperature, we use the equation:

$q=mc\Delta T$ .........(1)

where,

q = heat absorbed

m = mass of substance

$c$ = specific heat capacity of substance

$\Delta T$ = change in temperature

To calculate the amount of heat required at same temperature, we use the equation:

$q=m\times \Delta H$ ........(2)

where,

q = heat absorbed

m = mass of substance

$\Delta H$ = enthalpy of the reaction

The processes involved in the given problem are:

$1.)C_2H_5OH(l)(35^oC)\rightarrow C_2H_5OH(l)(78^oC)\\2.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)$

For process 1:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=35^oC\\\Delta T=[T_2-T_1]=[78-35]^oC=43^oC=43K$

Putting values in equation 1, we get:

$q_1=42.0g\times 2.3J/g.K\times 43K\\\\q_1=4153.8J$

For process 2:

We are given:

Conversion factor: 1 kJ = 1000 J

Molar mass of ethanol = 46 g/mol

$m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{35.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g$

Putting values in equation 2, we get:

$q_2=42.0g\times 773.04J/g\\\\q_2=32467.7J$

Total heat required = $[q_1+q_2]$

Total heat required = $[4153.8J+32467.7J]=36621.5J$

Hence, the total heat required is 36621.5 J

For b:

The processes involved in the given problem are:

$1.)C_2H_5OH(s)(-155^oC)\rightarrow C_2H_5OH(s)(-144^oC)\\2.)C_2H_5OH(s)(-144^oC)\rightarrow C_2H_5OH(l)(-144^oC)\\3.)C_2H_5OH(l)(-144^oC)\rightarrow C_2H_5OH(l)(78^oC)\\4.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)$

For process 1:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_s=0.97J/g.K\\T_2=-144^oC\\T_1=-155^oC\\\Delta T=[T_2-T_1]=[-144-(-155)]^oC=11^oC=11K$

Putting values in equation 1, we get:

$q_1=42.0g\times 0.97J/g.K\times 11K\\\\q_1=448.14J$

For process 2:

We are given:

$m=42.0g\\\Delta H_{fusion}=5.02kJ/mol=\frac{5.02kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=109.13J/g$

Putting values in equation 2, we get:

$q_2=42.0g\times 109.13J/g\\\\q_2=4583.5J$

For process 3:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=-144^oC\\\Delta T=[T_2-T_1]=[78-(-144)]^oC=222^oC=222K$

Putting values in equation 1, we get:

$q_3=42.0g\times 2.3J/g.K\times 222K\\\\q_3=21445.2J$

For process 4:

We are given:

$m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{38.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g$

Putting values in equation 2, we get:

$q_4=42.0g\times 773.04J/g\\\\q_4=32467.7J$

Total heat required = $[q_1+q_2+q_3+q_4]$

Total heat required = $[448.14+4583.5+21445.2+32467.7]J=58944.5J$

Hence, the total heat required is 58944.5 J

8 0

3 years ago

An unknown salt is either NaF, NaCl, or NaOCl. When 0.050 mol of the salt is dissolved in water to form 0.500 L of solution, the

victus00 [196]

Answer: The unknown salt is NaF

Explanation:

To calculate the molarity of solution, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of salt = 0.050 moles

Volume of solution = 0.500 L

Putting values in above equation, we get:

$\text{Molarity of salt}=\frac{0.050mol}{0.500L}\\\\\text{Molarity of salt}=0.1M$

To calculate the hydroxide ion concentration, we first calculate pOH of the solution, which is:

pH + pOH = 14

We are given:

pH = 8.08

$pOH=14-8.08=5.92$

To calculate pOH of the solution, we use the equation:

$pOH=-\log[OH^-]$

Putting values in above equation, we get:

$5.92=-\log[OH^-]$

$[OH^-]=10^{-5.92}=1.202\times 10^{-6}M$

The unknown salt given are formed by the combination of weak acid and strong acid which is NaOH

The chemical equation for the hydrolysis of $X^-$ ions follows:

$X^-(aq.)+H_2O(l)\rightleftharpoons HX(aq.)+OH^-(aq.);K_b$

Initial: 0.1

At eqllm: 0.1-x x x

Concentration of $OH^-=x=1.202\times 10^{-6}M$

The expression of $K_b$ for above equation follows:

$K_b=\frac{[OH^-][HX]}{[X^-]}$

Putting values in above expression, we get:

$K_b=\frac{(1.202\times 10^{-6})\times (1.202\times 10^{-6})}{(1-(1.202\times 10^{-6}))}\\\\K_b=1.445\times 10^{-11}M$

To calculate the acid dissociation constant for the given base dissociation constant, we use the equation:

$K_w=K_b\times K_a$

where,

$K_w$ = Ionic product of water = $10^{-14}$

$K_a$ = Acid dissociation constant

$K_b$ = Base dissociation constant = $1.445\times 10^{-11}$

Putting values in above equation, we get:

$10^{-14}=1.445\times 10^{-11}\times K_a\\\\K_a=\frac{10^{-14}}{1.445\times 10^{-11}}=6.92\times 10^{-4}$

We know that:

$K_a\text{ for HF}=6.8\times 10^{-6}$

$K_a\text{ for HCl}=1.3\times 10^{6}$

$K_a\text{ for HClO}=3.0\times 10^{-8}$

So, the calculated $K_a$ is approximately equal to the $K_a$ of HF

Hence, the unknown salt is NaF

6 0

3 years ago

In the periodic table, how are elements in the same group related to each other? A. They have the same atomic mass. B. They have

Irina-Kira [14]

Elements in the same group tend to have very similar properties (D). This is due to the number of valence electrons each group has.

3 0

2 years ago

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A car travels 66 kilometers in 3 hours. what is its speed

Ne4ueva [31]

Answer:

22 kph

Explanation:

You simply divide the distance and the time. 66/3 = 22.

8 0

3 years ago

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