The two half-reactions are...
Ag→Ag+
and...
NO3→NO
Let's start by balancing the first half-reaction...
Ag→Ag+
The amounts are already balanced; 1:1. The oxygens are balanced. So all that's left is to balance the charge...
Ag→Ag++e−
Now let's do the other equation... Amounts of nitrogen are balanced, so we first need to balance the oxygens...
NO3→NO
4H++NO3→NO+2H2O
Next, we need to balance charge...
4e−+4H++NO3→NO+2H2O
Now let's go ahead and rewrite each half-reaction after being balanced by themselves...
Ag→Ag++e−
4e−+4H++NO3→NO+2H2O
Now we need to multiply by some factor to get the electrons to cancel out. In this case, that factor is 4, which needs to be applied to the top half-reaction...
4(Ag→Ag++e−)=4Ag→4Ag++4e−
Then we combine this half-reaction with the second one above to get...
4Ag+4H++NO3→4Ag++NO+2H2O
Answer:
90.3 kJ/mol
Explanation:
Let's consider the following thermochemical equation.
2 NO(g) + O₂(g) → 2 NO₂(g) ∆H°rxn = –114.2 kJ
We can find the standard enthalpy of formation for NO using the following expression.
∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g)) - 1 mol × ΔH°f(O₂(g))
∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g)) - 1 mol × 0 kJ/mol
∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g))
ΔH°f(NO(g)) = (2 mol × ΔH°f(NO₂(g)) - ∆H°rxn) / 2 mol
ΔH°f(NO(g)) = (2 mol × 33.2 kJ/mol + 114.2 kJ) / 2 mol
ΔH°f(NO(g)) = 90.3 kJ/mol
Answer:
A) Dilute the unknown so that it will have an absorbance within the standard curve. Once the diluted unknown concentration is determined, the full strength concentration can be calculated if the dilution process is recorded. Beer's law only applies to dilute solutions, so diluting the unknown is better than making new standards.
Explanation:
Beer's law states that <em>absorbance is proportional to the concentrations of the absorbing species</em>. This is verified in the case of diluted solutions (0≤0.01 M) of most substances. <u>As a solution gets more concentrated, solute molecules interact between themselves because of their proximity. </u>When a molecule interacts with another, the change in their electric properties (including absorbance) is probable. That's why <u>the plot of absorbance versus concentration stops being a straight line</u>, and <u>Beer's law is no longer valid.</u>
Therefore, if the absorbance value is higher than the highest standard, dilutions should be made. Once this concentration is determined, the full strength concentration can be calculated with the inverse of the dilution.
Its Concentration, diffusion, a selectively Premable membrane, osmosis,diffusion, a selectively permeable membrane, osmosis, and diffusion
