In a combustion of a hydrocarbon compound, 2 reactions are happening per element:
C + O₂ → CO₂
2 H + 1/2 O₂ → H₂O
Thus, we can determine the amount of C and H from the masses of CO₂ and H₂O produced, respectively.
1.) Compute for the amount of C in the compound. The data you need to know are the following:
Molar mass of C = 12 g/mol
Molar mass of CO₂ = 44 g/mol
Solution:
0.5008 g CO₂*(1 mol CO₂/ 44 g)*(1 mol C/1 mol CO₂) = 0.01138 mol C
0.01138 mol C*(12 g/mol) = 0.13658 g C
Compute for the amount of H in the compound. The data you need to know are the following:
Molar mass of H = 1 g/mol
Molar mass of H₂O = 18 g/mol
Solution:
0.1282 g H₂O*(1 mol H₂O/ 18 g)*(2 mol H/1 mol H₂O) = 0.014244 mol H
0.014244 mol H*(1 g/mol) = 0.014244 g H
The percent composition of pure hydrocarbon would be:
Percent composition = (Mass of C + Mass of H)/(Mass of sample) * 100
Percent composition = (0.13658 g + 0.014244 g)/(<span>0.1510 g) * 100
</span>Percent composition = 99.88%
2. The empirical formula is determined by finding the ratio of the elements. From #1, the amounts of moles is:
Amount of C = 0.01138 mol
Amount of H = 0.014244 mol
Divide the least number between the two to each of their individual amounts:
C = 0.01138/0.01138 = 1
H = 0.014244/0.01138 = 1.25
The ratio should be a whole number. So, you multiple 4 to each of the ratios:
C = 1*4 = 4
H = 1.25*4 = 5
Thus, the empirical formula of the hydrocarbon is C₄H₅.
3. The molar mass of the empirical formula is
Molar mass = 4(12 g/mol) + 5(1 g/mol) = 53 g/mol
Divide this from the given molecular weight of 106 g/mol
106 g/mol / 53 g/mol = 2
Thus, you need to multiply 2 to the subscripts of the empirical formula.
Molecular Formula = C₈H₁₀
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Answer:
0.42%
Explanation:
<em>∵ pH = - log[H⁺].</em>
2.72 = - log[H⁺]
∴ [H⁺] = 1.905 x 10⁻³.
<em>∵ [H⁺] = √Ka.C</em>
∴ [H⁺]² = Ka.C
∴ ka = [H⁺]²/C = (1.905 x 10⁻³)²/(0.45) = 8.068 x 10⁻⁶.
<em>∵ Ka = α²C.</em>
Where, α is the degree of dissociation.
<em>∴ α = √(Ka/C) </em>= √(8.065 x 10⁻⁶/0.45) = <em>4.234 x 10⁻³.</em>
<em>∴ percentage ionization of the acid = α x 100</em> = (4.233 x 10⁻³)(100) = <em>0.4233% ≅ 0.42%.</em>
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