Energy can accomplish work
Answers:
1. 3-ethyl-3-methylheptane; 2. 2,2,3,3-tetramethylpentane; 3. hexa-2,4-diene.
Explanation:
<em>Structure 1
</em>
- Identify and name the longest continuous chain of carbon atoms (the main chain has 7 C; ∴ base name = heptane).
- Identify and name all the substituents [a 1C substituent (methyl) and a 2C substituent (methyl).
- Number the main chain from the end closest to a substituent.
- Identify the substituents by the number of the C atom on the main chain. Use hyphens between letters and numbers (3-methyl, 3-ethyl).
- Put the names of the substituents in alphabetical order in front of the base name with no spaces (3-ethyl-3-methylheptane)
<em>Structure 2</em>
- 5C. Base name = pentane
- Four methyl groups.
- Number from the left-hand end.
- If there is more than one substituent of the same type, identify each substituent by its locating number and use a multiplying prefix to show the number of each substituent. Use commas between numbers (2,2,3,3-tetramethyl).
- The name is 2,2,3,3-tetramethylpentane.
<em>Structure 3
</em>
- Identify and name the longest continuous chain of carbon atoms that passes through as many double bonds as possible. Drop the <em>-ne</em> ending of the alkane to get the root name <em>hexa-</em>.
- (No substituents).
- Number the main chain from the end closest to a double bond.
- If there is more than one double bond use a multiplying prefix to indicate the number of double bonds (two double bonds = diene) and use the smaller of the two numbers of the C=C atoms as the double bond locators (2,4-diene)
- Put the functional group name at the end of the root name (hexa-2,4-diene).
<em>Note</em>: The name 2,4-hexadiene is <em>acceptable</em>, but the <em>Preferred IUPAC Name</em> puts the locating numbers as close as possible in front of the groups they locate.
The reaction is
CaC₂(s) + 2H₂O (l) -----> Ca(OH)₂ (s) + C₂H₂ (g)
As we have data of gas ethyne (or acetylene), C₂H₂
We can calculate the moles of acetylene and from this we can estimate the mass of calcium carbide taken
the moles of acetylene will be calculated using ideal gas equation
PV =nRT
R = gas constant = 0.0821 Latm/molK
T = 385 K
V = volume = 550 L
P = Pressure = 1.25 atm
n = moles = ?
n = PV /RT = 1.25 X 550 / 0.0821 X 385 = 21.75 mol
As per balanced equation these moles of acetylene will be obtained from same moles of calcium carbide
moles of calcium carbide = 21.75mol
molar mass of CaC₂ = 40 + 24 = 64
mass of CaC₂ = moles X molar mass = 21.75 X 64 = 1392g