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goldfiish [28.3K]
3 years ago
11

Which equation shows conservation of mass and energy for a reaction at 101.3 kpa and 298 k?

Chemistry
2 answers:
harkovskaia [24]3 years ago
3 0

Answer is: a.2h2(g) + o2(g) 2h2o(g) + 483.6 kj.

Conservation of mass (mass is never lost or gained in chemical reactions), during chemical reaction no particles are created or destroyed, the atoms are rearranged from the reactants to the products.

The law of conservation of energy states that the total energy of an isolated system remains constant; energy can neither be created nor destroyed; it can only be transformed or transferred from one form to another.

Balanced chemical reaction: 2H₂ + O₂ → 2H₂O ΔH = 483.6 kJ.

There are four hydrogen atoms and two oxygen atoms on both side of balanced chemical reaction.

const2013 [10]3 years ago
3 0
C and D are not correctly balanced so it is not show conservation of energy also for B the energy value is not correct it is not show conservation of mass and energy so the correct answer is A:
2 H₂(g) + O₂(g) → 2 H₂O(g) +483.6 kJ
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4 years ago
A 25.0 ml sample of a 0.2900 m solution of aqueous trimethylamine is titrated with a 0.3625 m solution of hcl. calculate the ph
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a) After adding 10 mL of HCl

first, we need to get moles of (CH3)3N = molarity * volume

                                                                 = 0.29 m * 0.025 L
                                                                 = 0.00725M moles
then, we need to get moles of HCl = molarity * volume

                                                          = 0.3625 m * 0.01L
                                                          = 0.003625 moles

so moles of (CH3)3N remaining    = moles of (CH3)3N - moles of HCl
                                                         = 0.00725 - 0.003625

                                                      = 0.003625 moles

and when the total volume = 0.01 L + 0.025L = 0.035 L

∴ [(CH3)3N] = moles remaining / total volume

                    = 0.003625 moles / 0.035L
                    = 0.104 M

when we have Pkb so we can get Kb :

pKb = - ㏒Kb
4.19 = -㏒Kb

∴Kb = 6.5 x 10^-5

when Kb = [(CH3)3NH+] [OH-] / [(CH3)3N]

and by using ICE table we assume we have:

[(CH3)3NH+] = X & [OH] = X 

and [(CH3)3N] = 0.104 -X

by substitution:

∴ 6.5 x 10^-5 = X^2 / (0.104-X)  by solving for X

∴X = 0.00257 M
∴[OH-] = X = 0.00257 M

∴POH = -㏒[OH]

           = -㏒0.00257
           = 2.5

∴ PH = 14 - POH
         = 14 - 2.5
         = 11.5
b) after adding 20ML of HCL:

moles of HCl = molarity * volume
                       = 0.3625 m * 0.02 L

                       = 0.00725 moles

  

the complete neutralizes of (CH3)3N we make 0.003625 moles of (CH3)3NH+ So, now we need the Ka value of (CH3)3NH+:

and when the total volume = 0.02L + 0.025 = 0.045L

∴ [ (CH3)3NH+] = moles / total volume

                          = 0.003625 / 0.045L
                          = 0.08 M
 
when Ka = Kw / Kb 

and we have Kb = 6.5 x 10^-5 & we know that Kw = 1 x 10^-14 

so, by substitution:

Ka = (1 x 10^-14) / (6.5 x 10^-5)

    = 1.5 x 10^-10


when Ka expression = [(CH3)3N][H+] / [(CH3)3NH+]

by substitution:

∴ 1.5 x 10^-10 = X^2 / (0.08 - X)  by solving for X

∴X = 3.5 x 10^-6  M

∴ [H+]= X = 3.5 x 10^-6 M

∴PH = -㏒[H+]

        = -㏒(3.5 x 10^-6)

       = 5.5


C) after adding 30ML of HCl:

moles of HCl = molarity * volume 

                       = 0.3625m * 0.03L

                       = 0.011 moles

and when moles of (CH3)3N neutralized = 0.003625 moles 

∴ moles of HCl remaining    = moles HCl - moles (CH3)3N neutralized

                                                = 0.011moles - 0.003625moles

                                                = 0.007375 moles
when total volume = 0.025L + 0.03L

                                = 0.055L

∴[H+] = moles / total volume

           = 0.007375 mol / 0.055L

            = 0.134 M

∴PH = -㏒[H+]

        = -㏒ 0.134

        = 0.87
8 0
3 years ago
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