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Y_Kistochka [10]
3 years ago
12

In a hexagonal-close-pack (hcp) unit cell, the ratio of lattice points to octahedral holes to tetrahedral holes is 1:1:2. What i

s the general formula for a compound if anions occupy the hcp lattice points and cations occupy half of the tetrahedral holes? AB A3B AB2 A2B What is the general formula for a compound if anions occupy the hcp lattice points and cations occupy all the tetrahedral holes? AB A2B AB2 A3B
Chemistry
1 answer:
Alex777 [14]3 years ago
6 0

Explanation:

In a hexagonal-close-pack (HCP) unit cell, the ratio of lattice points to octahedral holes to tetrahedral holes =  1 : 1 : 2

let the :

Number of lattice point = 1x.

Number of octahedral points = 1x

Number of tetrahedral  points = 2x

If anions occupy the HCP lattice points and cations occupy half of the tetrahedral holes.

Number of anions occupying the HCP lattice points, A= 1x

Number of cations occupying the tetrahedral points, B =  \frac{2x}{2}=x

The formula of the compound will be = A_{1x}B_{1x}=AB

If anions occupy the HCP lattice points and cations occupy all of the tetrahedral holes.

Number of anions occupying the HCP lattice points, A= 1x

Number of cations occupying the tetrahedral points, B =  2x

The formula of the compound will be = A_{1x}B_{2x}=AB_2

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A 0.590 gram sample of a metal, M, reacts completely with sulfuric acid according to:M(s) +H2SO4(aq) --&gt; MSO4(aq) +H2(g)A vol
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MM = 58.41 g

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First, the data we have is according to the hydrogen which is exerting pressure. To solve this, we need to use the ideal gas equation:

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However, before we do all that, we need to gather all the correct data.

All the species in the reaction are solid or aqueous state, with the exception of hydrogen, which is gaseous. Hydrogen is collected over water, therefore, is exerting some pressure too. The problem is not indicating if the acid or any other species is exerting pressure, so we will assume that only hydrogen and water are exerting pressure.

The total pressure exerted by the system would be:

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We already know the total pressure which is 756 torr.

This experiment is taking place at 25 °C (298.15 K), and at this temperature, we have a reported value for water pressure which is 23.8 Torr.

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Now, with this value, and the volume and temperature, we can calculate the moles of H2:

n = PV/RT

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PH2 = 733 Torr / 760 torr * 1 atm = 0.9644 atm

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n = 0.9644 * (0.255) / 0.082 * 298.15

n = 0.0101 moles

Now that we have the moles, we know that the metal and the hydrogen has a mole ratio of 1:1 according to the reaction, so, this means that:

moles M = moles H2 = 0.0101 moles

We have the moles of the metal and the mass, we can calculate the molar mass using expression (2):

MM = 0.590/0.0101

MM = 58.41 g/mol

This is the molar mass of the metal

8 0
3 years ago
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Answer:

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<em><u>Using cross multiplication:</u></em>

1.0 mole of CO occupies → 22.4 L.

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∴ The volume of water vapor in 36.21 g = (22.4 L)(2.01 mole) / (1.0 mole) = 45.02 L.

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