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motikmotik
3 years ago
10

Consider the following equilibrium:

Chemistry
1 answer:
Ainat [17]3 years ago
7 0

<u>Answer: </u>The equation which is wrong is K_p=K_c(RT)^{-5}

<u>Explanation:</u>

For the given reaction:

4Fe(s)+3O_2(g)\rightarrow 2Fe_2O_3(s)

The expression for K_c\text{ and }K_p is given by:

K_c=\frac{1}{[O_2]^3}

K_p=\frac{1}{[O_2]^3}

The concentration of solids are taken to be 1, only concentration of gases and liquid states are taken. The pressure of only gases are taken.

Relationship between K_p\text{ and }K_c is given by the expression:

K_p=K_c\times (RT)^{\Delta n_g}

where,

\Delta n_g= number of moles of gaseous products - number of moles of gaseous reactants

R = gas constant

T= temperature

For the above reaction,

\Delta n_g = number of moles of gaseous products - number of moles of gaseous reactants = 0 - 3 = -3

Hence, the expression for K_p is:

K_p=K_c\times (RT)^{-3}

Therefore, the equation which is wrong is K_p=K_c(RT)^{-5}

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Burning 12.00 g of an oxoacid produces 17.95 g of carbon dioxide and 4.87 g of water. Consider that 0.25
Veseljchak [2.6K]

Answer: The molecular formula will be C_6H_6O_6

Explanation:

Mass of CO_2 = 17.95 g

Mass of H_2O= 4.87 g

Molar mass of carbon dioxide = 44 g/mol

Molar mass of water = 18 g/mol

For calculating the mass of carbon:

In 44g of carbon dioxide, 12 g of carbon is contained.

So, in 17.95 g of carbon dioxide, =\frac{12}{44}\times 17.95=4.89g of carbon will be contained.

For calculating the mass of hydrogen:

In 18g of water, 2 g of hydrogen is contained.

So, in 4.87 g of water, =\frac{2}{18}\times 4.87=0.541g of hydrogen will be contained.

Mass of oxygen in the compound = (12.00) - (4.89+0.541) = 6.57 g

Mass of C = 4.89 g

Mass of H =  0.541 g

Mass of O = 6.57 g

Step 1 : convert given masses into moles.

Moles of C =\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{4.89g}{12g/mole}=0.407moles

Moles of H=\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{0.541g}{1g/mole}=0.541moles

Moles of O=\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{6.57g}{16g/mole}=0.410moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C =\frac{0.407}{0.407}=1

For H =\frac{0.541}{0.407}=1

For O = \frac{0.410}{0.407}=1

The ratio of C : H : O = 1: 1  : 1

Hence the empirical formula is CHO.

Hence the empirical formula is CHO

The empirical weight of CHO = 1(12)+1(1)+1(16)= 29 g.

If 0.25 moles has mass of 44.0 g

Thus 1 mole has mass of = \frac{44.0}{0.25}\times 1=176g

Thus molecular mass is 176 g

Now we have to calculate the molecular formula.

n=\frac{\text{Molecular weight }}{\text{Equivalent weight}}=\frac{176g}{29g}=6

The molecular formula will be=6\times CHO=C_6H_6O_6

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Calcium hydroxide is a strong base but is not very soluble ( Ksp = 5.02 X 10-6 ). What is the pH of a saturated solution of Ca(O
Misha Larkins [42]

Answer : The pH of a saturated solution is, 12.33

Explanation : Given,

K_{sp} = 5.02\times 10^{-6}

First we have to calculate the solubility of OH^- ion.

The balanced equilibrium reaction will be:

Ca(OH)_2\rightleftharpoons Ca^{2+}+2OH^-

Let the solubility will be, 's'.

The concentration of Ca^{2+} ion = s

The concentration of OH^- ion = 2s

The expression for solubility constant for this reaction will be,

K_{sp}=[Ca^{2+}][OH^-]^2

Let the solubility will be, 's'

K_{sp}=(s)\times (2s)^2

K_{sp}=(4s)^3

Now put the value of K_[sp} in this expression, we get the solubility.

5.02\times 10^{-6}=(4s)^3

s=1.079\times 10^{-2}M

The concentration of Ca^{2+} ion = s = 1.079\times 10^{-2}M

The concentration of OH^- ion = 2s = 2\times (1.079\times 10^{-2}M)=2.158\times 10^{-2}M

First we have to calculate the pOH.

pOH=-\log [OH^-]

pOH=-\log (2.158\times 10^{-2})

pOH=1.67

Now we have to calculate the pH.

pH+pOH=14\\\\pH=14-pOH\\\\pH=14-1.67=12.33

Therefore, the pH of a saturated solution is, 12.33

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3 years ago
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