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zhuklara [117]
3 years ago
7

A 24.00 mL sample of a solution of Pb(ClO3)2 was diluted with water to 52.00 mL. A 17.00 mL sample of the dilute solution was fo

und to contain 0.220 M ClO3−(aq). What was the concentration of Pb(ClO3)2 in the original undiluted solution? 3.60 × 10−2 M 7.19 × 10−2 M 0.238 M 0.156 M 0.477 M
Chemistry
1 answer:
lara [203]3 years ago
6 0

Answer:

0.238 M

Explanation:

A 17.00 mL sample of the dilute solution was found to contain 0.220 M ClO₃⁻(aq). The concentration is an intensive property, so the concentration in the 52.00 mL is also 0.220 M ClO₃⁻(aq). We can find the initial concentration of ClO₃⁻ using the dilution rule.

C₁.V₁ = C₂.V₂

C₁ × 24.00 mL = 0.220 M × 52.00 mL

C₁ = 0.477 M

The concentration of Pb(ClO₃)₂ is:

\frac{0.477molClO_{3}^{-} }{L} \times \frac{1molPb(ClO_{3})_{2}}{2molClO_{3}^{-}} =0.238M

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<u>Answer:</u> The freezing point of solution is -0.454°C

<u>Explanation:</u>

Depression in freezing point is defined as the difference in the freezing point of pure solution and freezing point of solution.

The equation used to calculate depression in freezing point follows:

\Delta T_f=\text{Freezing point of pure solution}-\text{Freezing point of solution}

To calculate the depression in freezing point, we use the equation:

\Delta T_f=iK_fm

Or,

\text{Freezing point of pure solution}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}

where,

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i = Vant hoff factor = 2

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M_{solute} = Molar mass of solute (KCl) = 74.55 g/mol

W_{solvent} = Mass of solvent (water) = 550.0 g

Putting values in above equation, we get:

0-\text{Freezing point of solution}=2\times 1.86^oC/m\times \frac{5\times 1000}{74.55g/mol\times 550}\\\\\text{Freezing point of solution}=-0.454^oC

Hence, the freezing point of solution is -0.454°C

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