The reaction between a strong acid and a weak base produces a salt, but water is not usually formed because:

1. The pressure of a gas is 100.0 kPa and its volume is 500.0 ml. If the volume increases to 1,000.0 ml, what is the new pressur

marta [7]

Answer:

1) The new pressure of the gas is 500 kilopascals.

2) The final volume is 1.44 liters.

3) Volume will decrease by approximately 67 %.

4) The Boyle's Laws deals with pressures and volumes.

Explanation:

1) From the Equation of State for Ideal Gases we construct the following relationship:

$\frac{P_{2}}{P_{1}} = \frac{V_{1}}{V_{2}}$ (1)

Where:

$P_{1}, P_{2}$ - Initial and final pressure, measured in kPa.

$V_{1}, V_{2}$ - Initial and final pressure, measured in mililiters.

If we know that $P_{1} = 100\,kPa$ , $V_{1} = 500\,mL$ and $V_{2} = 1000\,mL$ , then the new pressure of the gas is:

$P_{2} = P_{1}\cdot \left(\frac{V_{1}}{V_{2}} \right)$

$P_{2} = 500\,kPa$

The new pressure of the gas is 500 kilopascals.

2) Let suppose that gas experiments an isothermal process. From the Equation of State for Ideal Gases we construct the following relationship:

$\frac{P_{2}}{P_{1}} = \frac{V_{1}}{V_{2}}$ (1)

Where:

$P_{1}, P_{2}$ - Initial and final pressure, measured in kPa.

$V_{1}, V_{2}$ - Initial and final pressure, measured in mililiters.

If we know that $V_{1} = 3.60\,L$ , $P_{1} = 10\,kPa$ and $P_{2} = 25\,kPa$ then the new volume of the gas is:

$V_{2} = V_{1}\cdot \left(\frac{P_{1}}{P_{2}} \right)$

$V_{2} = 1.44\,L$

The final volume is 1.44 liters.

3) From the Equation of State for Ideal Gases we construct the following relationship:

$\frac{P_{2}}{P_{1}} = \frac{V_{1}}{V_{2}}$ (1)

Where:

$P_{1}, P_{2}$ - Initial and final pressure, measured in kPa.

$V_{1}, V_{2}$ - Initial and final pressure, measured in mililiters.

If we know that $\frac{P_{2}}{P_{1}} = 3$ , then the volume ratio is:

$\frac{V_{1}}{V_{2}} = 3$

$\frac{V_{2}}{V_{1}} = \frac{1}{3}$

Volume will decrease by approximately 67 %.

4) The Boyle's Laws deals with pressures and volumes.

8 0

2 years ago

Sodium tert-butoxide (NaOC(CH3)3) is classified as bulky and acts as Bronsted Lowry base in the reaction. It is reacted with 2-c

IceJOKER [234]

Answer:but-1-ene

Explanation:This is an E2 elimination reaction .

Kindly refer the attachment for complete reaction and products.

Sodium tert-butoxide is a bulky base and hence cannot approach the substrate 2-chlorobutane from the more substituted end and hence major product formed here would not be following zaitsev rule of elimination reaction.

Sodium tert-butoxide would approach from the less hindered side that is through the primary centre and hence would lead to the formation of 1-butene .The major product formed in this reaction would be 1-butene .

As the mechanism of the reaction is E-2 so it will be a concerted mechanism and as sodium tert-butoxide will start abstracting the primary hydrogen through the less hindered side simultaneously chlorine will start leaving. As the steric repulsion in this case is less hence the transition state is relatively stabilised and leads to the formation of a kinetic product 1-butene.

Kinetic product are formed when reactions are dependent upon rate and not on thermodynamical stability.

2-butene is more thermodynamically6 stable as compared to 1-butene

The major product formed does not follow the zaitsev rule of forming a more substituted alkene as sodium tert-butoxide cannot approach to abstract the secondary proton due to steric hindrance.