For the crystallization purpose the combination of solvent process is known to be an effective process. But the solvent pair one have to choose crucially. The solvent which is completely in soluble into the other solvent can not work as a good solvent pair for the crystallization. The crystallization of any compound by the solvent pair process is depend upon the slow diffusion of a less polar solvent to the polar solvent or vice-versa.
If a compound is soluble in a polar solvent the slow diffusion of relatively low polar solvent will make crystal of the compound. But anyhow the solvents which are completely not immiscible to each other will not work for the purpose. Thus diethyl ether and water solvent pair can not be used for the crystallization process.
Answer:
Concentration of unknown solution is 0.0416 M
Explanation:
As we know
Absorbance is equal to the product of molar absorptivity of KMnO4 m, path length and concentration
From the given set of graphical data, it is clear that the absorbance vs concentration is a straight line.
From the graph, we can obtain-
Y = 5.73 X – 0.0065
Absorbance = 0.232
0.232 = 5.73 X – 0.0065
X = 0.0416
Concentration of unknown solution is 0.0416 M
Answer:
1.65 L
Explanation:
The equation for the reaction is given as:
A + B ⇄ C
where;
numbers of moles = 0.386 mol C (g)
Volume = 7.29 L
Molar concentration of C = 
= 0.053 M
A + B ⇄ C
Initial 0 0 0.530
Change +x +x - x
Equilibrium x x (0.0530 - x)
![K = \frac{[C]}{[A][B]}](https://tex.z-dn.net/?f=K%20%3D%20%5Cfrac%7B%5BC%5D%7D%7B%5BA%5D%5BB%5D%7D)
where
K is given as ; 78.2 atm-1.
So, we have:
![78.2=\frac{[0.0530-x]}{[x][x]}](https://tex.z-dn.net/?f=78.2%3D%5Cfrac%7B%5B0.0530-x%5D%7D%7B%5Bx%5D%5Bx%5D%7D)
Using quadratic formula;
where; a = 78.2 ; b = 1 ; c= - 0.0530
= 
or 
= 
or 
= 0.0204 or -0.0332
Going by the positive value; we have:
x = 0.0204
[A] = 0.0204
[B] = 0.0204
[C] = 0.0530 - x
= 0.0530 - 0.0204
= 0.0326
Total number of moles at equilibrium = 0.0204 + 0.0204 + 0.0326
= 0.0734
Finally, we can calculate the volume of the cylinder at equilibrium using the ideal gas; PV =nRT
if we make V the subject of the formula; we have:
where;
P (pressure) = 1 atm
n (number of moles) = 0.0734 mole
R (rate constant) = 0.0821 L-atm/mol-K
T = 273.15 K (fixed constant temperature )
V (volume) = ???
V = 1.64604
V ≅ 1.65 L
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