Answer:
V = 2.32 Liters
Explanation:
PV = nRT => V = nRT/P
n = 25.8g/122g/mole = 0.21 mole
R = 0.08206 L·atm/mol·K
T = 25.44°C + 273 = 298.44K
P = 2.22 atm (given in problem)
V = (0.21mol)(0.08206 L·atm/mol·K)(298.44K)/(2.22atm) = 2.32 Liters at 25.44°C & 2.22atm
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Number of moles is defined as the ratio of given mass in g to the molar mass.
The mathematical formula is:
Number of moles =
(1)
Number of zinc atoms is equal to
, by Avogadro number, number of moles can be calculated.
As, 1 mol=
atoms, hence,

= 0.2822 mol
Now, from formula (1), calculate mass in g (molar mass of zinc = 65.4 g/mol)
0.2822 mol =
mass in g = 
= 18.45588 g
Thus, by rounding off the above number, it will come near about 19 g approximately.
Hence, option (C) is the correct answer.