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slavikrds [6]
3 years ago
13

A 2.300×10−2 m solution of nacl in water is at 20.0∘c. the sample was created by dissolving a sample of nacl in water and then b

ringing the volume up to 1.000 l. it was determined that the volume of water needed to do this was 999.4 ml . the density of water at 20.0∘c is 0.9982 g/ml.
Chemistry
1 answer:
lilavasa [31]3 years ago
8 0

The given question is incomplete. The complete question is as follows.

A 2.300×10−2 m solution of nacl in water is at 20.0∘c. the sample was created by dissolving a sample of nacl in water and then bringing the volume up to 1.000 l. it was determined that the volume of water needed to do this was 999.4 ml . the density of water at 20.0∘c is 0.9982 g/ml.

Calculate the molality of the salt solution.

Express your answer to four significant figures and include the appropriate units.

Explanation:

Molality is defined as the number of moles present in kg of a solvent.

Mathematically,     Molality = \frac{\text{moles of solute}}{\text{mass of solvent}}

Also,

      Mole of solute = Molarity of solute x Volume of solution

                               = (0.0230 M) x (1.000 L) = 0.0230 mol of solute

Therefore, mass of solvent will be as follows.

     999.4 mL \times (\frac{0.9983 g}{1 mL})

                  = 997.7 g

                  = 0.9977 kg        (as 1 kg = 1000 g)

Therefore, we will calculate the molality as follows.

          Molality = \frac{0.0230 mol}{0.9977 kg}

                   = 0.02306 mol/kg

thus, we can conclude that molality of the given solution is 0.02306 mol/kg.

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Find the enthalpy of neutralization of HCl and NaOH. 87 cm3 of 1.6 mol dm-3 hydrochloric acid was neutralized by 87 cm3 of 1.6 m
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Answer : The correct option is, (A) -101.37 KJ

Explanation :

First we have to calculate the moles of HCl and NaOH.

\text{Moles of HCl}=\text{Concentration of HCl}\times \text{Volume of solution}=1.6mole/L\times 0.087L=0.1392mole

\text{Moles of NaOH}=\text{Concentration of NaOH}\times \text{Volume of solution}=1.6mole/L\times 0.087L=0.1392mole

The balanced chemical reaction will be,

HCl+NaOH\rightarrow NaCl+H_2O

From the balanced reaction we conclude that,

As, 1 mole of HCl neutralizes by 1 mole of NaOH

So, 0.1392 mole of HCl neutralizes by 0.1392 mole of NaOH

Thus, the number of neutralized moles = 0.1392 mole

Now we have to calculate the mass of water.

As we know that the density of water is 1 g/ml. So, the mass of water will be:

The volume of water = 87ml+87ml=174ml

\text{Mass of water}=\text{Density of water}\times \text{Volume of water}=1g/ml\times 174ml=174g

Now we have to calculate the heat absorbed during the reaction.

q=m\times c\times (T_{final}-T_{initial})

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q = heat absorbed = ?

c = specific heat of water = 4.18J/g^oC

m = mass of water = 174 g

T_{final} = final temperature of water = 317.4 K

T_{initial} = initial temperature of metal = 298 K

Now put all the given values in the above formula, we get:

q=174g\times 4.18J/g^oC\times (317.4-298)K

q=14110.008J=14.11KJ

Thus, the heat released during the neutralization = -14.11 KJ

Now we have to calculate the enthalpy of neutralization.

\Delta H=\frac{q}{n}

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\Delta H = enthalpy of neutralization = ?

q = heat released = -14.11 KJ

n = number of moles used in neutralization = 0.1392 mole

\Delta H=\frac{-14.11KJ}{0.1392mole}=-101.37KJ/mole

Therefore, the enthalpy of neutralization is, -101.37 KJ

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