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allsm [11]
3 years ago
10

Which of the following substances is the most soluble in water?

Chemistry
2 answers:
GuDViN [60]3 years ago
5 0
A. Sodium Chloride.
brilliants [131]3 years ago
5 0

Answer: A. Sodium chloride

Explanation: Sodium chloride (NaCl) is an ionic compound formed by transfer of electrons from sodium to chlorine.

Electronic configuration of sodium:

[Na]=1s^22s^22p^63s^1

Sodium atom will loose one electron to gain noble gas configuration and form sodium cation with +1 charge.

[Na^+]=1s^22s^22p^63s^0

Electronic configuration of chlorine:

[Cl]=1s^22s^22p^63s^23p^5

Chlorine atom will gain one electron to gain noble gas configuration and form chloride ion with -1 charge.

[Cl^-]=1s^22s^22p^63s^23p^6

These ions can be separated in polar solvent water and thus are soluble in water.

Whereas methane (CH_4) is a covalent compound formed by sharing of electrons and is soluble in non polar solvents.

Bromine (Br_2) is a covalent compound formed by sharing of electrons and is soluble in non polar solvents.

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Calculate the pH for each of the following cases in the titration of 50.0 mL of 0.210 M HClO(aq) with 0.210 M KOH(aq).
Degger [83]
a) before addition of any KOH : 

when we use the Ka equation & Ka = 4 x 10^-8 : 

Ka = [H+]^2 / [ HCIO]

by substitution:

4 x 10^-8 = [H+]^2 / 0.21

[H+]^2 = (4 x 10^-8) * 0.21

           = 8.4 x 10^-9

[H+] = √(8.4 x 10^-9)

       = 9.2 x 10^-5 M

when PH = -㏒[H+]

   PH = -㏒(9.2 x 10^-5)

        = 4  

b)After addition of 25 mL of KOH: this produces a buffer solution 

So, we will use Henderson-Hasselbalch equation to get PH:

PH = Pka +㏒[Salt]/[acid]


first, we have to get moles of HCIO= molarity * volume

                                                           =0.21M * 0.05L

                                                           = 0.0105 moles

then, moles of KOH = molarity * volume 

                                  = 0.21 * 0.025

                                  =0.00525 moles 

∴moles HCIO remaining = 0.0105 - 0.00525 = 0.00525

and when the total volume is = 0.05 L + 0.025 L =  0.075 L

So the molarity of HCIO = moles HCIO remaining / total volume

                                        = 0.00525 / 0.075

                                        =0.07 M

and molarity of KCIO = moles KCIO / total volume

                                    = 0.00525 / 0.075

                                    = 0.07 M

and when Ka = 4 x 10^-8 

∴Pka =-㏒Ka

         = -㏒(4 x 10^-8)

         = 7.4 

by substitution in H-H equation:

PH = 7.4 + ㏒(0.07/0.07)

∴PH = 7.4 

c) after addition of 35 mL of KOH:

we will use the H-H equation again as we have a buffer solution:

PH = Pka + ㏒[salt/acid]

first, we have to get moles HCIO = molarity * volume 

                                                        = 0.21 M * 0.05L

                                                        = 0.0105 moles

then moles KOH = molarity * volume
                            =  0.22 M* 0.035 L 

                            =0.0077 moles 

∴ moles of HCIO remaining = 0.0105 - 0.0077=  8 x 10^-5

when the total volume = 0.05L + 0.035L = 0.085 L

∴ the molarity of HCIO = moles HCIO remaining / total volume 

                                      = 8 x 10^-5 / 0.085

                                      = 9.4 x 10^-4 M

and the molarity of KCIO = moles KCIO / total volume

                                          = 0.0077M / 0.085L

                                          = 0.09 M

by substitution:

PH = 7.4 + ㏒( 0.09 /9.4 x 10^-4)

∴PH = 8.38

D)After addition of 50 mL:

from the above solutions, we can see that 0.0105 mol HCIO reacting with 0.0105 mol KOH to produce 0.0105 mol KCIO which dissolve in 0.1 L (0.5L+0.5L) of the solution.

the molarity of KCIO = moles KCIO / total volume

                                   = 0.0105mol / 0.1 L

                                   = 0.105 M

when Ka = KW / Kb

∴Kb = 1 x 10^-14 / 4 x 10^-8

       = 2.5 x 10^-7

by using Kb expression:

Kb = [CIO-] [OH-] / [KCIO]

when [CIO-] =[OH-] so we can substitute by [OH-] instead of [CIO-]

Kb = [OH-]^2 / [KCIO] 

2.5 x 10^-7 = [OH-]^2 /0.105

∴[OH-] = 0.00016 M

POH = -㏒[OH-]

∴POH = -㏒0.00016

           = 3.8
∴PH = 14- POH

        =14 - 3.8

PH = 10.2

e) after addition 60 mL of KOH:

when KOH neutralized all the HCIO so, to get the molarity of KOH solution

M1*V1= M2*V2

 when M1 is the molarity of KOH solution

V1 is the total volume = 0.05 + 0.06 = 0.11 L

M2 = 0.21 M 

V2 is the excess volume added  of KOH = 0.01L

so by substitution:

M1 * 0.11L = 0.21*0.01L

∴M1 =0.02 M

∴[KOH] = [OH-] = 0.02 M

∴POH = -㏒[OH-]

           = -㏒0.02 

           = 1.7

∴PH = 14- POH

       = 14- 1.7 

      = 12.3 
8 0
3 years ago
Read 2 more answers
How many valence electrons are in Lithium
denpristay [2]
Lithium has 3 electrons
4 0
3 years ago
Read 2 more answers
Which of the following elements is commonly found in the Earth's crust, living matter, oceans, and atmosphere? hydrogen , neon g
Svetlanka [38]

Answer: hydrogen

Explanation: hydrogen gas is a major component of water which occupies a large portion of the Earth's atmosphere

4 0
3 years ago
What is the volume of 1.56 kg of a compound whose molar mass is 81.86 g/mole and whose density is 41.2 g/ml?
hjlf

Answer:

v = 37.9 ml

Explanation:

Given data:

Mass of compound = 1.56 kg

Density = 41.2 g/ml

Volume of compound = ?

Solution:

First of all we will convert the mass into g.

1.56 ×1000 = 1560 g

Formula:

D=m/v

D= density

m=mass

V=volume

v = m/d

v =  1560 g / 41.2 g/ml

v = 37.9 ml

7 0
3 years ago
What is meant by the ground state of an atom? What is meant by the ground state of an atom? All of the quantum numbers have thei
ANTONII [103]

Answer: Option (a) is the correct answer.

Explanation:

We know that ground state means in total electrons acquired by the element are present in their lowest energy level.

We calculate the azimutal numbers as follows.

                      n = l + 1

where,     n = principle quantum number  

                l = azimuthal quantum number

Values of n can be 1, 2, 3, 4 and so on. Whereas the values of l can be 0, 1, 2, 3, and so on.

Also, "m" is known as magnetic quantum number whose values can be equal to -l and +l.  

So, when n = 1 then l = 0 and m = 0.

When n = 2 then l = 1 and values of m will be equal to -1, 0, +1. As it is given that the magnetic quantum number ml = -1. Hence, it is only possible when n = 2.

And, n = 1 is the lowest energy level. Therefore, we can conclude that the ground state of an atom means all of the quantum numbers have their lowest values (n = 1,ℓ = mℓ = 0).

5 0
3 years ago
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