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grin007 [14]
3 years ago
14

Consider the following reaction: 2 H2(g) + 2 NO(g) → 2 H2O(g) + N2(g) If the concentration of NO changed from 0.100 M to 0.025 M

in the first 15 minutes of the reaction, what is the average rate of the reaction during this time interval?
Chemistry
1 answer:
Wewaii [24]3 years ago
6 0

Answer: The average rate of the reaction during this time interval is, 0.005 M/s

Explanation:

The given chemical reaction is:

2H_2(g)+2NO(g)\rightarrow 2H_2O(g)+N_2(g)

The expression will be:

\text{Average rate of reaction}=\frac{C_2-C_1}{t_2-t_1}

where,

C_2 = final concentration of NO = 0.025 M

C_1 = initial concentration of NO = 0.100 M

t_2 = final time = 15 minutes

t_1 = initial time = 0 minutes

Putting values in above equation, we get:

\text{Average rate of reaction}=\frac{0.025-0.100}{15-0}

\text{Average rate of reaction}=0.005M/s

Hence, the average rate of the reaction during this time interval is, 0.005 M/s

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2) 2.5 mol of an ideal gas at 20 oC under 20 atm pressure, was expanded up to 5 atm pressure via; (a) adiabatic reversible and (
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Answer:

a) for adiabatic reversible, ΔU(internal energy is constant) = 0, ΔH = 0(no heat is entering or leaving the surrounding)

workdone (w) = -8442.6 J  ≈ -8.443 KJ

heat transferred (q) of the ideal gas = - w

q = 8.443 KJ

b) For ideal gas at adiabatic reversible, Internal energy (ΔU) = 0 and enthalpy (ΔH) = 0

the workdone(w) in the ideal gas= - 4567.5 J  ≈ - 4.57 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

Explanation:

given

mole of an ideal gas(n) = 2.5 mol

Temperature (T) = 20°C

= (20°C + 273) K  = 293 K

Initial pressure of the ideal gas(P₁) = 20 atm

Final pressure of the ideal gas(P₂) = 5 atm.

2) (a)for adiabatic reversible process,

note: adiabatic process is a process by which no heat or mass is transferred between the system and its surrounding.

Work done (w) = nRT ln\frac{P_{1} }{P_{2} }

= 2.5 mol × 8.314 J/mol K × 293 K × ln\frac{5atm}{20atm}

= 6090.01 J × [-1.3863]

= -8442.6 J  ≈ -8.443 KJ

So, the work done (w) of ideal gas = -8.443 KJ

For ideal gas at adiabatic reversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-8.443 KJ)

q = 8.443 KJ

heat transfer (q) of the ideal gas = 8.443 KJ

(b) For adiabatic irreversible, the temperature T remains constant because the internal energy U depends only on temperature T. Since at constant temperature, the entropy is proportional to the volume, therefore, entropy will increase.

Work done (w) = -nRT(1 - ln\frac{P_{1} }{P_{2} } )

= - 2.5 mol × 8.314 J / mol K× 293 K × [1- (5 atm /20 atm)]

= - 6090.01 J × 0.75

= - 4567.5 J  ≈ - 4.57 KJ

∴work done(w) of an ideal gas = - 4.57 KJ

For ideal gas at adiabatic Irreversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-4.5675 KJ)

q = 4.5675 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

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A 1.000 g sample of an unknown hydrate of cobalt chloride is gently dehydrated. The resulting mass is 0.546 g. The cobalt is iso
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Answer:

Explanation:

From the 1 g sample you have:

0.546 grams of cobalt chloride

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Now:

1) The salt

Of the 0.546 g, 0.248 g are cobalt (Mr=58.9) and the rest id Cl (Mr=35.45):

n_{Co}=\frac{0.248 g}{58.9 g/mol}=4.21*10^{-3}mol

n_{Cl}=\frac{0.298 g}{35.45g/mol}=8.4*10^{-3}mol

Dividing:

\frac{n_{Cl}}{n_{Co}}=\frac{8.4*10^{-3}mol}{4.21*10^{-3}mol}=2

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CoCl_2

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The water's molecular weight is M=18 :

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Bonding with the Co:

\frac{n_{w}}{n_{Co}}=\frac{0.025mol}{4.21*10^{-3}mol}=6

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