How water leaves the atmosphere
2 answers:
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The provided information are:
volume of 0.85 M lactic acid = 225 ml
volume of 0.68 M sodium lactate = 435 ml
Ka of the lactate buffer = 1.38 x 10⁻⁴
The equation for dissociation of lactic acid is:
CH₃CH(OH)COOH(aq) + H₂O ⇄ CH₃CH(OH)COO⁻(aq) + H₃O⁺(aq)
The pH of buffer is calculated from Henderson-Hasselbalch equation, which is:
pH = pKa + log![\frac{[conjugated base]}{[Acid]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5Bconjugated%20base%5D%7D%7B%5BAcid%5D%7D%20)
pKa = - log Ka = - log (1.38 x 10⁻⁴) = 3.86
The number of moles of lactic acid and lactate are as follows:
n (Lactic acid) = 225 ml x 0.85 mmol/ml = 191.25 mmol
n (Lactate) = 435 ml x 0.68 mmol/ml = 295.8 mmol
The number of moles of lactic acid and lactate in total volume of the solution:
[CH₃CH(OH)COOH] = n (lactic acid) / 660 ml = 191.25 mmol / 660 ml = 0.29 M
[CH₃CH(OH)COO⁻] = n (lactate) / 660 ml = 0.45 M
pH = 3.86 + log
= 3.86 + 0.191 = 4.05
So the pH of given solution is 4.05
volume of 0.85 M lactic acid = 225 ml
volume of 0.68 M sodium lactate = 435 ml
Ka of the lactate buffer = 1.38 x 10⁻⁴
The equation for dissociation of lactic acid is:
CH₃CH(OH)COOH(aq) + H₂O ⇄ CH₃CH(OH)COO⁻(aq) + H₃O⁺(aq)
The pH of buffer is calculated from Henderson-Hasselbalch equation, which is:
pH = pKa + log
pKa = - log Ka = - log (1.38 x 10⁻⁴) = 3.86
The number of moles of lactic acid and lactate are as follows:
n (Lactic acid) = 225 ml x 0.85 mmol/ml = 191.25 mmol
n (Lactate) = 435 ml x 0.68 mmol/ml = 295.8 mmol
The number of moles of lactic acid and lactate in total volume of the solution:
[CH₃CH(OH)COOH] = n (lactic acid) / 660 ml = 191.25 mmol / 660 ml = 0.29 M
[CH₃CH(OH)COO⁻] = n (lactate) / 660 ml = 0.45 M
pH = 3.86 + log
So the pH of given solution is 4.05
Answer:
W=-37.6kJ, therefore, work is done on the system.
Explanation:
Hello,
In this case, the first step is to compute the moles of each gas present in the given mixture, by using the total mixture weight the mass compositions and their molar masses:
Next, the total moles:
After that, since the process is isobaric, we can compute the work as:
Therefore, we need to compute both the initial and final volumes which are at 260 °C and 95 °C respectively for the same moles and pressure (isobaric closed system)
Thereby, the magnitude and direction of work turn out:
Thus, we conclude that since it is negative, work is done on the system (first law of thermodynamics).
Regards.