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irina [24]
3 years ago
15

If you are given an ideal gas with pressure (p)259,392.00 pa and temperature (T)=200°c of 1 mole Argon gas in a volume 8.8dm3,ca

lculate R to the correct number of significant figure and units under given conditions
Chemistry
1 answer:
GuDViN [60]3 years ago
4 0

Answer: R=4.82436 \frac{Pa. m^{3}}{mol. K}

Explanation:

The Ideal Gas equation is:  

P.V=n.R.T  (1)

Where:  

P is the pressure of the gas  

n the number of moles of gas  

R=8.3144598 \frac{Pa. m^{3}}{mol. K} is the gas constant  

T is the absolute temperature of the gas in Kelvin.

V is the volume

It is important to note that the behavior of a real gas is far from that of an ideal gas, taking into account that <u>an ideal gas is a single hypothetical gas</u>. However, under specific conditions of standard temperature and pressure (T=0\°C=273.15 K and P=1 atm=101,3 kPa) one mole of real gas (especially in noble gases such as Argon) will behave like an ideal gas and the constant R will be 8.3144598 \frac{Pa. m^{3}}{mol. K}.

However, in this case we are not working with standard temperature and pressure, therefore, even if we are working with Argon, the value of R will be far from the constant of the ideal gases.

Having this clarified, let's isolate R from (1):

R=\frac{PV}{nT}  (2)

Where:

P=259392 Pa

n=1 mole

T=200\°C=473.15 K is the absolute temperature of the gas in Kelvin.

V=8.8 dm^{3}=0.0088 m^{3}

R=\frac{(259392 Pa)(0.0088 m^{3})}{(1 mole)(473.15 K)}  (3)

Finally:

R=4.82436 \frac{Pa. m^{3}}{mol. K}  

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It will be easiest to balance this equation by the ion-electron method.

1. Write the ionic equation

PbO₂ + Mn²⁺ + SO₄²⁻ + H⁺ + NO₃⁻ ⟶ H⁺ + MnO₄⁻ + Pb²⁺ + SO₄²⁻ + Pb²⁺ + NO₃⁻ + H₂O

2. Eliminate H⁺, H₂O, and spectator ions

PbO₂ + Mn²⁺ ⟶ MnO₄⁻ + Pb²⁺  

3. Separate the skeleton equation into two half-reactions.

PbO₂  ⟶ Pb²⁺  

Mn²⁺ ⟶ MnO₄⁻

4. Balance all atoms other than H and O

Done

5. Balance O by adding water molecules to the deficient side

           PbO₂  ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻

6. Balance H by adding H⁺ ions to the deficient side.

  PbO₂+ 4H⁺ ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺

7. Balance charge by adding electrons to the deficient side.

PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O

     Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e-

 

8. Multiply each half-reaction by a number to equalize the electrons transferred.

5 × [PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O]

     2 × [Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e⁻]

9. Add the two half-reactions.

                          5PbO₂+ 20H⁺ + 10e⁻ ⟶ 5Pb²⁺ + 10H₂O

<u>                                    2Mn²⁺ + 8H₂O ⟶ 2MnO₄⁻ + 16H⁺ + 10e⁻                    </u>

5PbO₂ + 2Mn² + 8H₂O + 20H⁺ + 10e⁻⟶ 5Pb²⁺ + 2MnO₄⁻ + 10H₂O + 16H⁺ + 10e⁻

10. Cancel species that occur on each side of the equation

5PbO₂ + 2Mn² + <u>8H₂O</u> + <u>20H⁺</u> + <u>10e⁻</u> ⟶ 5Pb²⁺ + 2MnO₄⁻ + <u>10H₂O</u> + <u>16H⁺</u> + <u>10e⁻ </u>

becomes

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11. Add the missing spectator ions

5PbO₂ + 2Mn²⁺    + 4H⁺                              ⟶            5Pb²⁺   + 2MnO₄⁻ + 2H₂O

            + 2SO₄²⁻ + 4NO₃⁻ + 2H⁺ + 2NO₃⁻       +2SO₄²⁻ + 6NO₃⁻ + 2H⁺

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12. Check that all atoms are balanced.

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Everything checks. The balanced equation is

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄ + 2H₂O

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Explanation:

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