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algol [13]
3 years ago
14

What is the ph of a 0.15 m solution of ammonium chloride?

Chemistry
1 answer:
Thepotemich [5.8K]3 years ago
7 0
 Best Answer:  <span>(a) 
8.9 x 10^-7 = x^2 / 0.15-x 
x = [OH-] = 0.00037 M 
pOH = 3.4 
pH = 14 - 3.4 = 10.6 

(b) 
Ka = Kw/Kb = 5.6 x 10^-10 = x^2 / 0.20-x 
x = [H+] = 0.000011 M 
pH = 5.0</span>
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Balance the redox reaction Al(s) + MnO4^- (aq) --&gt; MnO2 (s) + Al(OH)4^- (aq) in aqueous basic solution
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Answer:

Al + MnO4- + 2H2O → Al(OH)4- + MnO2

Explanation:

First of all, we out down the skeleton equation;

Al + MnO4- → MnO2 + Al(OH)4-

Secondly, we write the oxidation and reduction equation in basic medium;

Oxidation half equation:Al + 4H2O + 4OH- → Al(OH)4- + 4H2O + 3e-

Reduction half equation:MnO4- + 4H2O + 3e- → MnO2 + 2H2O + 4OH-

Thirdly, we add the two half reactions together to obtain:

Al + MnO4- + 8H2O + 4OH- + 3e- → Al(OH)4- + MnO2 + 6H2O + 3e- + 4OH-

Lastly, cancel out species that occur on both sides of the reaction equation;

Al + MnO4- + 8H2O→ Al(OH)4- + MnO2 + 6H2O

The simplified equation now becomes;

Al + MnO4- + 2H2O → Al(OH)4- + MnO2

4 0
3 years ago
Given these reactions, where X represents a generic metal or metalloid 1 ) H 2 ( g ) + 1 2 O 2 ( g ) ⟶ H 2 O ( g ) Δ H 1 = − 241
anygoal [31]

Answer : The enthalpy of the given reaction will be, -1048.6 kJ

Explanation :

According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

The main reaction is:

XCl_4(s)+2H_2O(l)\rightarrow XO_2(s)+4HCl(g)    \Delta H=?

The intermediate balanced chemical reactions are:

(1) H_2(g)+\frac{1}{2}O_2(g)\rightarrow H_2O(g)     \Delta H_1=-241.8kJ

(2) X(s)+2Cl_2(g)\rightarrow XCl_4(s)    \Delta H_2=+461.9kJ

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(4) X(s)+O_2(g)\rightarrow XO_2(s)    \Delta H_4=-789.1kJ

(5) H_2O(g)\rightarrow H_2O(l)    \Delta H_5=-44.0kJ

Now reversing reaction 2, multiplying reaction 3 by 4, reversing reaction 1 and multiplying by 2, reversing reaction 5 and multiplying by 2 and then adding all the equations, we get :

(1) 2H_2O(g)\rightarrow 2H_2(g)+O_2(g)     \Delta H_1=2\times 241.8kJ=483.6kJ

(2) XCl_4(s)\rightarrow X(s)+2Cl_2(g)    \Delta H_2=-461.9kJ

(3) 2H_2(g)+2Cl_2(g)\rightarrow 4HCl(g)    \Delta H_3=4\times -92.3kJ=-369.2kJ

(4) X(s)+O_2(g)\rightarrow XO_2(s)    \Delta H_4=-789.1kJ

(5) 2H_2O(l)\rightarrow 2H_2O(g)    \Delta H_5=2\times 44.0kJ=88.0kJ

The expression for enthalpy of main reaction will be:

\Delta H=\Delta H_1+\Delta H_2+\Delta H_3+\Delta H_4+\Delta H_5

\Delta H=(483.6)+(-461.9)+(-369.2)+(-789.1)+(88.0)

\Delta H=-1048.6kJ

Therefore, the enthalpy of the given reaction will be, -1048.6 kJ

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