Answer:
1. The dye that absorbs at 530 nm.
Explanation:
The dye will absorb light to promote the transition of an electron from the HOMO to the LUMO orbital.
The higher the gap, the higher the energy of transition. The energy can be calculated by E = hc/λ, in which h and c are constants and λ is the wavelength.
The equation shows that the higher the energy, the higher the gap and the lower the wavelength.
Therefore, the dye with absorption at 530 nm has the higher HOMO-LUMO gap.
The dichloromethane (DCM) has less density than water and also the polarity of water is much more than DCM. So the mixture of water and dichloromethane will always be a heterogeneous mixture. In the mixture dichloromethane will be always up of the water layer. The volume of the separatory funnel which contains the mixture of DCM and water must have to be more than the total volume of the liquids thus the volume of the funnel will be more than (50+50) = 100mL.
The caution have to consider during the separation are-
1. The separatory funnel have to shake well with lid and have to settle down for some times until the two liquid separated.
2. The lid should be open very slowly as the vapor pressure of DCM is more and it will float on the water.
3. After this the stopcock should be opened and slowly the water will come out first followed by DCM.
Pan 4: theyre the smallest and most broken down :)
It is important because if the sample size is smaller, outliers could skew the data more than if it was large.
37.8 grams of CS2 equals to 37.8/76=0.5 mole. So the products have 0.5 mole CO2 which is 11.2 liters at STP. So according to the gas law, the volume at given condition is 12.4 liters. So the answer should be 12.2 liters.
