Answer:-
Solution:- As is clear from the given Ka value, Cinnamic acid is a weak acid. let's calculate the moles of acid and KOH added to it from their given molarities and mL.
For KOH, 
= 0.002 mol
For Cinnamic acid, 
= 0.003 mol
Acid and base react as:

The reaction takes place in 1:1 mol ratio. Since the moles of acid are in excess, the acid is still remaining when all the kOH is used.
0.002 moles of KOH react with 0.002 moles of Cinnamic acid to form 0.002 moles of potassium cinnamate. Excess moles of Cinnamic acid = 0.003 - 0.002 = 0.001
As the solution have weak acid and it's salt(or we could say conjugate base), it is a buffer solution and the pH of the buffer solution could easily be calculated using Handerson equation:

pKa could be caluted from given Ka value using the formula:
pKa = - log Ka

pKa = 4.44
let's plug in the values in Handerson equation and calculate the pH:

pH = 4.44+0.30
pH = 4.74
So, the first choice is correct, pH is 4.74.
Answer:
2.67 g/mL
Explanation:
Initial Volume of water = 10.0 mL
Final Volume pf water = 15.46 mL
Mass = 14.74g
Density = Mass / Volume of aluminium
Volume of aluminium = Final Volume of water - Initial Volume of water = 15.46 - 10 = 5.46mL
Density = 14.74 / 5.46 = 2.67 g/mL
I think it would have 10 neutrons. Hope this helps :)
Ionic crystals are hard because of tight packing lattices, say, the positive and negative ions are strongly attached among themselves.
If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change to reestablish equilibrium. If a chemical reaction is at equilibrium and experiences a change in pressure, temperature, or concentration of products or reactants, the equilibrium shifts in the opposite direction to offset the change. This page covers changes to the position of equilibrium due to such changes and discusses briefly why catalysts have no effect on the equilibrium position.
For example, if the system is changed in a way that increases the concentration of one of the reacting species, it must favor the reaction in which that species is consumed. In other words, if there is an increase in products, the reaction quotient, Qc, is increased, making it greater than the equilibrium constant, Kc.