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andreev551 [17]
3 years ago
12

Which electron transition represents a gain of energy

Chemistry
1 answer:
Helen [10]3 years ago
3 0

Answer:

The transition from lower energy level to higher energy level require a gain of energy.

Explanation:

When transition occur from lower energy level to higher energy level require a gain of energy. Electron could not jump unto higher energy level without gaining thew energy.

When electron jump into lower energy level from high energy level it loses the energy.

For example electron when jumped from 2nd to 3rd shell it gain energy and when in return back to 2nd shell from 3rd shell it loses energy.

The process is called excitation and de-excitation.

Excitation:

When the energy is provided to the atom the electrons by absorbing the energy jump to the higher energy levels. This process is called excitation. The amount of energy absorbed by the electron is exactly equal to the energy difference of orbits.

De-excitation:

When the excited electron fall back to the lower energy levels the energy is released in the form of radiations. this energy is exactly equal to the energy difference between the orbits. The characteristics bright colors are due to the these emitted radiations. These emitted radiations can be seen if they are fall in the visible region of spectrum.

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The question is incomplete. Complete question is attached below
..............................................................................................................................

Correct Answer: Option C i.e. I ~ III < IV < V < II

Reason:
During a nucleophilic subsitution reaction of chloroarenes, Cl- group is replaced by an nucleophile like OH-.

Order of reactivity, during such reactions depends on the electron density on carbon atom that is attached to Cl. Lower the electron density, greater will be the reactivity.

Among the provided chloroarenes, electron density on C atom will be minimum in case of compound II, because of presence of electron withdrawing group (-NO2) at ortho and para position. Due to this, there will be large number of resonating structures. This signifies greater electron de-localization, and hence largest reactivity for nucleophilic substitution reaction.

Followed by this, compound V will show greater reactivity, due to presence of -NO2 group at para and one of the ortho position. Compound IV will have less number of resonating structures as compared to compound II and V, hence it will display poor reactivity towards nucleophilic substitution reaction.

Finally, compound 1 and III will minimum reactivity towards nucleophilic substitution reaction, because -NO2 group present at meta position (compound III) will not participate in resonance.  



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