The balanced equation for the reaction is as follows
Na₂CO₃ + 2HCl --> 2NaCl + CO₂ + H₂O
stoichiometry of Na₂CO₃ to HCl is 1:2
number of Na₂CO₃ moles reacted = molarity x volume
number of Na₂CO₃ moles = 0.100 mol/L x 0.750 L = 0.0750 mol
according to molar ratio of 1:2
1 mol of Na₂CO₃ reacts with 2 mol of HCl
then 0.0750 mol of Na₂CO₃ mol reacts with - 2 x 0.0750 = 0.150 mol
molarity of given HCl solution is 1.00 mol/L
molarity is defined as the number of moles of solute in 1 L of solution
there are 1.00 mol in 1 L of solution
therefore there are 0.150 mol in - 0.150 mol / 1.00 mol/L = 0.150 L
volume of HCl required is 0.150 L
According to the reversible reaction equation:
2Hi(g) ↔ H2(g) + i2(g)
and when Keq is the concentration of the products / the concentration of the reactants.
Keq = [H2][i2]/[Hi]^2
when we have Keq = 1.67 x 10^-2
[H2] = 2.44 x 10^-3
[i2] = 7.18 x 10^-5
so, by substitution:
1.67 x 10^-2 = (2.44 x 10^-3)*(7.18x10^-5)/[Hi]^2
∴[Hi] = 0.0033 M
The factors that affect the rate of a reaction are:
- <em>nature of the reactant</em> - when reactants with different chemical composition are exposed to same conditions they would react differently. For instance, when an acid or base is added on litmus paper, blue litmus paper turns red in presence of acid while red litmus paper turns blue when base is added.
- <em>surface area</em>- a compound with small pieces spread over a large area will react faster than a big lump of a compound occupying a small area.
- <em>temperature of reaction</em>- reactants would react faster at high temperatures. this is because they have higher kinetic energy to collide with each other. Hence a plate of food on the table spoils faster than a plate of food in the fridge.
- <em>concentration</em>- an increase in concentration leads to more molecules available to collide and form products. An example, when you add more of indicator in a solution, the color becomes more clear since more particles react to give more color.
- <em>presence of a catalyst</em>- a catalyst lowers the activation energy, which means less energy is required to shift reaction in forward direction. In the presence of iron (Fe) a catalyst, nitrogen N₂ and hydrogen H₂ react to produce NH₃
