Answer:
0.057 M
Explanation:
Step 1: Given data
Solubility product constant (Ksp) for HgBr₂: 2.8 × 10⁻⁴
Concentration of mercury (II) ion: 0.085 M
Step 2: Write the reaction for the solution of HgBr₂
HgBr₂(s) ⇄ Hg²⁺(aq) + 2 Br⁻
Step 3: Calculate the bromide concentration needed for a precipitate to occur
The Ksp is:
Ksp = 2.8 × 10⁻⁴ = [Hg²⁺] × [Br⁻]²
[Br⁻] = √(2.8 × 10⁻⁴/0.085) = 0.057 M
Answer:
The reaction is not spontaneous in the forward direction, but in the reverse direction.
Explanation:
<u>Step 1: </u>Data given
H2(g) + I2(g) ⇌ 2HI(g) ΔG° = 2.60 kJ/mol
Temperature = 25°C = 25+273 = 298 Kelvin
The initial pressures are:
pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
<u>Step 2</u>: Calculate ΔG
ΔG = ΔG° + RTln Q
with ΔG° = 2.60 kJ/mol
with R = 8.3145 J/K*mol
with T = 298 Kelvin
Q = the reaction quotient → has the same expression as equilibrium constant → in this case Kp = [p(HI)]²/ [p(H2)] [p(I2)]
with pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
Q = (3.10²)/(1.5*1.75)
Q = 3.661
ΔG = ΔG° + RTln Q
ΔG = 2600 J/mol + 8.3145 J/K*mol * 298 K * ln(3.661)
ΔG =5815.43 J/mol = 5.815 kJ/mol
To be spontaneous, ΔG should be <0.
ΔG >>0 so the reaction is not spontaneous in the forward direction, but in the reverse direction.
Kilauea volcano in Hawaii emits 200-300 tons of sulfur dioxide into the atmosphere each day. This is an example of
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Kilauea volcano in Hawaii emits noxious compounds of sulfur dioxide and other harmful pollutants as a result of a reaction with atmospheric water vapors and oxygen.
This reaction results in acid rain and volcanic smog which pollutes the air.
Over the years, the volcano has become a potential threat to health as harmful oxides are accelerating respiratory problems and acid rain destroys crops, and also harms water supplies.
If you need to learn more about the Kilauea volcano click here:
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