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Xelga [282]
3 years ago
7

How much energy is required to convert 15.0 g of ice at −106 °C to water vapor at 125 °C? Specific heats are 2.09 J/g K for both

ice and water vapor, and 4.18 J/g K for liquid water. Heats of vaporization and fusion are 2.260 kJ/g and 0.335 kJ/g, respectively.
Chemistry
1 answer:
myrzilka [38]3 years ago
4 0

Answer:

49.3 kJ of energy is required

Explanation:

An exercise of calorimetry at its best

First of all, convert the ice to water before melting.

Q = ice mass . C . ΔT

Q = 15 g . 2.09 J/g°C (0° - (-106°C)

15 g . 2.09 J/g°C . 106°C = 3323.1 J

Now we have to melt the ice, to change its state

Q = mass . latent heat of fusion

Q = 15 g . 0.335 kJ/g = 5.025 kJ .1000 = 5025 J

After that, we have liquid water at 0° and the ice has melted completely. We have to release energy to make a temperature change, to 100° (vaporization)

Q = 15g . 4.18 J/g°C (100°C - 0°C)

Q = 6270 J

Water has been vaporizated so we have to calculate, the state change.

Q = mass . latent heat of vap

Q = 15 g. 2.260 kJ/g

Q = 33.9 kJ (.1000) = 33900 J

Finally we have to increase temperature from 100°C to 125°C

Q = 15 g . 2.09 J/g°C . (125°C - 100°C)

Q = 783.75 J

To know how much energy is required to conver 15 g of ice, to water vapor at 125°C, just sum all the heat released.

3323.1 J + 5025 J + 6270 J + 33900 J + 783.75 J = 49301.85 joules.

Notice I have to convert kJ to J in two calcules to make the sum.

49301.85 joules / 1000 = 49.3 kJ

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8 0
3 years ago
When a student mixes 50 mL of 1.0 M HCl and 50 mL of 1.0 M NaOH in a coffee-cup calorimeter, the temperature of the resultant so
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Answer: 54.4 kJ/mol

Explanation:

First we have to calculate the moles of HCl and NaOH.

\text{Moles of HCl}=\text{Concentration of HCl}\times \text{Volume of solution}=1.0M\times 0.05=0.05mole

\text{Moles of NaOH}=\text{Concentration of NaOH}\times \text{Volume of solution}=1.0\times 0.05L=0.05mole

The balanced chemical reaction will be,

HCl+NaOH\rightarrow NaCl+H_2O

From the balanced reaction we conclude that,

As, 1 mole of HCl neutralizes by 1 mole of NaOH

So, 0.05 mole of HCl neutralizes by 0.05 mole of NaOH

Thus, the number of neutralized moles = 0.05 mole

Now we have to calculate the mass of water:

As we know that the density of water is 1 g/ml. So, the mass of water will be:

The volume of water = 50ml+50ml=100ml

\text{Mass of water}=\text{Density of water}\times \text{Volume of water}=1g/ml\times 100ml=100g

Now we have to calculate the heat absorbed during the reaction.

q=m\times c\times (T_{final}-T_{initial})

where,

q = heat absorbed = ?

c = specific heat of water = 4.18J/g^oC

m = mass of water = 100 g

T_{final} = final temperature of water = 27.5^0C

T_{initial} = initial temperature of metal = 21.0^0C

Now put all the given values in the above formula, we get:

q=100g\times 4.18J/g^oC\times (27.5-21.0)^0C

q=2719.6J=2.72kJ

Thus, the heat released during the neutralization = 2.72 KJ

Now we have to calculate the enthalpy of neutralization per mole of HCl:

0.05 moles of HCl releases heat = 2.72 KJ

1 mole of HCl releases heat =\frac{2.72}{0.05}\times 1=54.4KJ

Thus the enthalpy change for the reaction in kJ per mol of HCl is 54.4 kJ

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Answer:

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