Answer:
They decrease, because of the stronger effective nuclear charge.
Explanation:
- Atomic radii decreases from left to right across a period.
- This is due to the increase in the no. of protons and electrons through the period.
- One proton has a greater effect than one electron.
- So, electrons are attracted towards the nucleus and resulting in a smaller atomic radii.
<em>Thus, the right choice is: They decrease, because of the stronger effective nuclear charge.</em>
<em></em>
Answer:
Answers are in the explanation.
Explanation:
<em>Given concentrations are:</em>
- <em>SO₂ = 0.20M O₂ = 0.60M SO₃ = 0.60M</em>
- <em>SO₂ = 0.14M O₂ = 0.10M SO₃ = 0.40M </em>
- <em>And SO₂ = 0.90M O₂ = 0.50M SO₃ = 0.10M</em>
<em />
In the reaction:
2SO₂(g) + O₂(g) ⇄ 2SO₃(g)
Kc is defined as:
Kc = 15 = [SO₃]² / [O₂] [SO₂]²
<em>Where concentrations of each species are equilbrium concentrations.</em>
<em />
Also, you can define Q (Reaction quotient) as:
Q = [SO₃]² / [O₂] [SO₂]²
<em>Where concentrations of each species are ACTUAL concentrations.</em>
<em />
If Q > Kc, the reaction will shift to the left until Q = Kc;
If Q < Kc, the reaction will shift to the right until Q = Kc
If Q = Kc, there is no net reaction because reaction would be en equilibrium.
Replacing with given concentrations:
- Q = [0.60M]² / [0.60M] [0.20M]² = 15; Q = Kc → No net reaction
- Q = [0.40M]² / [0.10M] [0.14M]² = 82; Q > Kc, → Reaction will shift to the left
- Q = [0.10M]² / [0.50M] [0.90M]² = 0.015; Q < Kc → Reaction will shift to the right
<em />
Answer:
0.3229 M HBr(aq)
0.08436M H₂SO₄(aq)
Explanation:
<em>Stu Dent has finished his titration, and he comes to you for help with the calculations. He tells you that 20.00 mL of unknown concentration HBr(aq) required 18.45 mL of 0.3500 M NaOH(aq) to neutralize it, to the point where thymol blue indicator changed from pale yellow to very pale blue. Calculate the concentration (molarity) of Stu's HBr(aq) sample.</em>
<em />
Let's consider the balanced equation for the reaction between HBr(aq) and NaOH(aq).
NaOH(aq) + HBr(aq) ⇄ NaBr(aq) + H₂O(l)
When the neutralization is complete, all the HBr present reacts with NaOH in a 1:1 molar ratio.

<em>Kemmi Major also does a titration. She measures 25.00 mL of unknown concentration H₂SO₄(aq) and titrates it with 0.1000 M NaOH(aq). When she has added 42.18 mL of the base, her phenolphthalein indicator turns light pink. What is the concentration (molarity) of Kemmi's H₂SO₄(aq) sample?</em>
<em />
Let's consider the balanced equation for the reaction between H₂SO₄(aq) and NaOH(aq).
2 NaOH(aq) + H₂SO₄(aq) ⇄ Na₂SO₄(aq) + 2 H₂O(l)
When the neutralization is complete, all the H₂SO₄ present reacts with NaOH in a 1:2 molar ratio.
