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anzhelika [568]
3 years ago
12

Calculate the ph of a solution formed by mixing 200.0 ml of 0.30 m hclo with 300.0 ml of 0.20 m kclo. the ka for hclo is 2.9 × 1

0-8. 7.06 8.01 5.99 6.46
Chemistry
1 answer:
velikii [3]3 years ago
6 0
C(HClO) = 0,3 M.
<span>V(HClO) = 200 mL = 0,2 L.
n(HClO) = </span>c(HClO) · V(HClO).
n(HClO) = 0,06 mol.<span>
c(KClO</span>) = 0,2 M.
<span>V(KClO) = 0,3 L.
n(KClO) = 0,06 mol.
V(buffer solution) = 0,2 L + 0,3 L = 0,5 L.
ck</span>(HClO) = 0,06 mol ÷ 0,5 L = 0,12 M.
cs(KClO) = 0,06 mol ÷ 0,5 L = 0,12 M.<span>
Ka(HClO</span>) = 2,9·10⁻⁸.<span>
This is buffer solution, so use Henderson–Hasselbalch equation: 
pH = pKa + log(cs</span> ÷ ck).<span>
pH = -log(</span>2,9·10⁻⁸) + log(0,12 M ÷ 0,12 M).<span>
pH = 7,54 + 0.
pH = 7,54</span>
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