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Lilit [14]
3 years ago
7

If I have a 32 fl oz os a solution that has 62% alcohol, how much of a solution of 91% alcohol do I need to add to get a final s

olution of 90% alcohol?
Chemistry
1 answer:
laiz [17]3 years ago
8 0

Answer : The amount of solution needed is, 97.3 fl oz

Explanation :

Let the amount of solution needed be, x

Thus, the equation will be:

(x\times 0.62)+(32-x)\times 0.91=0.90

By solving the expression, we get the value of 'x'.

0.62x+0.91\times 32-0.91x=0.90

0.62x+29.12-0.91x=0.90

-0.29x+29.12=0.90

-0.29x=0.90-29.12

-0.29x=-28.22

0.29x=28.22

x=\frac{28.22}{0.29}

x=97.3

Therefore, the amount of solution needed is, 97.3 fl oz

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5 0
3 years ago
The protein lysozyme unfolds at a transition temperature of 75.5°C, and the standard enthalpy of transition is 509 kJ mol-1. Cal
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Answer:

0.4774 KJ/K.mol

Explanation:

We are told that the transition at 25.0°C occurs in three steps. Steps i, ii and iii.

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii

Now,

C_p,m(unfolded protein) = C_p,m(folded protein) + 6.28 kJ/K.mol

Now, for the first process, ΔS_i is given as;

ΔS_i = C_p,m × In(T2/T1)

We are given;

T1 = 25°C = 25 + 273.15K = 298.15 K

T2 = 75.5°C = 75.5 + 273.15 K=348.65 K

Thus;

ΔS_i = C_p,m × In(348.65/298.15)

Now, for the third process, ΔS_iii is given as;

ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(T1/T2)

Thus;

ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)

Now, we don't know C_pm. So, we have to find a way to eliminate it. We will do it by rewriting In(298.15/348.65) in such a way that when ΔS_iii is added to ΔS_i, C_p,m will cancel out. Thus;

In(298.15/348.65) can also be written as;

In(348.65/298.15)^(-1) or

- In(348.65/298.15)

Thus;

ΔS_iii = - [(C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)]

Now, let's add ΔS_iii to ΔS_i to get;

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] + [(-C_p,m - 6.28 kJ/K.mol) × In(348.65/298.15)]

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] - [C_p,m × In(348.65/298.15)] - [6.28In(348.65/298.15)]

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ΔS_i + ΔS_iii = -6.28In(348.65/298.15)

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ΔS_ii = (509 KJ/K.mol)/348.65

ΔS_ii = 1.46 KJ/K.mol

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii = -0.9826 + 1.46 = 0.4774 KJ/K.mol

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