The volume of H₃PO₄ : 13.33 ml
<h3>Further explanation</h3>
Given
0.003 M Phosphoric acid-H₃PO₄
40 ml of 0.00150 M Calcium hydroxide-Ca(OH)₂
Required
Volume of H₃PO₄
Solution
Acid-base titration formula
Ma. Va. na = Mb. Vb. nb
Ma, Mb = acid base concentration
Va, Vb = acid base volume
na, nb = acid base valence (amount of H⁺/OH⁻)
H₃PO₄⇒3H⁺ + PO₄³⁻ ⇒ 3 H⁺ = valence = 3
Ca(OH)₂⇒Ca²⁺ + 2OH⁻⇒ 2 OH⁻ = valence = 2
Input the value :
a = H₃PO₄, b = Ca(OH)₂
0.003 x Va x 3 = 0.0015 x 40 x 2
Va = 13.33 ml
Q: A
according to this formula, we can get the mole fraction of water (n):
P(solu) = n Pv(water)
when we have Pv(solu) = 22.8 and Pv(water) = 23.8 so by substitution:
22.8 = n * 23.8
n= 0.958
- we need to get the moles of glucose:
moles of water = 500 g(mass weight) / 18 (molar weight)= 27.7 mol
n = moles of water / ( moles of water + moles of glucose)
0.958 = 27.7 / ( 27.7+ moles of glucose)
0.958 moles of glucose + 26.5 = 27.7
0.968 moles of glucose = 1.2
moles of glucose = 1.253 mol
∴ the mass of glucose = no.of glucose moles x molar mass
= 1.253 x 180 = 225.5 g
Q: B
here we also need to get n (mole fraction of water )by using this formula:
Pv(solu) = n Pv(water)
when we have Pv(solu)=132 & Pv(water)=150 so, by substition:
132= n * 150
n = 0.88
so, mole fraction of solution = 1 - 0.88 = 0.12
and we can get after that the moles of water = (mass weight / molar mass)
- no.moles of water = 85 g / 18 g/mol = 4.7 moles
- total moles in solution = moles of water / moles fraction of water
= 4.7 / 0.88 = 5.34 moles
∴ moles of the solution = total moles in solu - moles of water
= 5.34 - 4.7 = 0.64 moles solute
∴ the molar mass of the solute = mass weight of solute / no.of moles of solute
= 53.8 / 0.64 = 84 g/mole
Q: C
moles of urea (NH2)2 CO = mass weight / molar mass
= 4.49 g / 60 g /mol
= 0.07 mol
moles of methanol = mass weight / molar mass
= 39.9 g / 32 g/mol = 1.25 mol
moles fraction of methanol = moles of methanol / (moles of methanol + moles of urea )
moles fraction of methanol = 1.25 / ( 1.25+0.07) = 0.95
by substitution in Pv formula we will be able to get the vapour pressure of the solu :
Pv(solu) = n P°v
Pv(solu) = 0.95 * 89 mm Hg
∴Pv(solu) = 84.55 mmHg
Answer:
15.35 g of (NH₄)₃PO₄
Explanation:
First we need to look at the chemical reaction:
3 NH₃ + H₃PO₄ → (NH₄)₃PO₄
Now we calculate the number of moles of ammonia (NH₃):
number of moles = mass / molecular wight
number of moles = 5.24 / 17 = 0.308 moles of NH₃
Now from the chemical reaction we devise the following reasoning:
if 3 moles of NH₃ are produce 1 mole of (NH₄)₃PO₄
then 0.308 moles of NH₃ are produce X moles of (NH₄)₃PO₄
X = (0.308 × 1) / 3 = 0.103 moles of (NH₄)₃PO₄
mass = number of moles × molecular wight
mass = 0.103 × 149 = 15.35 g of (NH₄)₃PO₄
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